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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sobczak, Szymon
Adam Mickiewicz University in Poznań
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024High-pressure observation of elusive iodoplumbic acid in different hydronium-hydrate solid formscitations
- 2024Temperature and volumetric effects on structural and dielectric properties of hybrid perovskitescitations
- 2024Unprecedented Richness of Temperature‐ and Pressure‐Induced Polymorphism in 1D Lead Iodide Perovskitecitations
- 2024Structural insight into piezo-solvatochromism of Reichardt's dyecitations
- 2023Engineering anomalous elastic properties of coordination polymers and their amorphization by employing flexible linkerscitations
- 2022Pressure-Driven Phase Transition in Two-Dimensional Perovskite MHy2PbBr4citations
- 2022Pressure-Driven Phase Transition in Two-Dimensional Perovskite MHy2PbBr4
- 2019Dynamic Resolution of Piezosensitivity in Single Crystals of π-Conjugated Moleculescitations
- 2019Environment-Controlled Postsynthetic Modifications of Iron Formate Frameworkscitations
- 2018Zone-Collapse Amorphization Mimicking the Negative Compressibility of a Porous Compoundcitations
- 2018Framework and coordination strain in two isostructural hybrid metal-organic perovskitescitations
Places of action
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article
Zone-Collapse Amorphization Mimicking the Negative Compressibility of a Porous Compound
Abstract
<p>A strongly anisotropic architecture of stacked metal-organic grids, with pores arranged through their eyes, has been revealed for the new coordination polymer Ni(bipy)(hip)(H<sub>2</sub>O)<sub>2</sub>·DMF·CH<sub>3</sub>OH·H<sub>2</sub>O, where bipy is 4,4′-bipyridine and hip is 5-hydroxyisophthalic acid. This porous crystal, when submerged in various nonpenetrating oils used as the hydrostatic media, displays a negative volume compressibility. This counterintuitive effect results in the zone amorphization injecting the contents of collapsing pores into the retained crystalline portions of the sample. This additional contents of the pores supports the crystalline parts and prevents their amorphization.</p>