| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Jouffret, Laurent
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024Corrosion of iron in liquid uranium hexafluoride at 80 °C. Part I: Normal and abnormal experimental kineticscitations
- 2019Synthesis, Structural, Spectroscopic, Thermal, Optical Studies and Hirshfeld Surface Analysis of a New Aluminum Complex: (C 8 H 9 N 2 ) 3 [Al(C 2 O 4 ) 3 ]·3H 2 Ocitations
- 2017Corrosion of iron in liquid uranium hexafluoridecitations
- 2016The influence of sacrificial carbonaceous supports on the synthesis of anhydrous NiF2 nanoparticles.citations
- 2016Corrosion mechanism of iron in liquid uranium hexafluoride environment
- 2015Evidence of New Fluorinated Coordination Compounds in the Composition Space Diagram of FeF3/ZnF2-Hamtetraz-HFaq System.citations
- 2014Fluoroferrates with ( dabco H2)2+ or (dabco H)+ Cationscitations
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article
Evidence of New Fluorinated Coordination Compounds in the Composition Space Diagram of FeF3/ZnF2-Hamtetraz-HFaq System.
Abstract
The exploration of the composition space diagram of the FeF3/ZnF2–Hamtetraz-HFaq system (Hamtetraz = 5-aminotetrazole) by solvothermal synthesis at 160 °C for 72 h in dimethylformamide (DMF) has evidenced five new hybrid fluorides (1–5); the structures are characterized from single crystal X-ray diffraction data. [Hdma]·(ZnFeIII(H2O)4F6) (1) and [Hdma]·[Hgua]2·(FeIIIF6) (2) contain anionic inorganic chains (1) or isolated octahedra (2) weakly hydrogen bonded (Class I hybrids) to dimethylammonium (Hdma) and/or guanidinium (Hgua) cations which are produced from the tetrazole ligand and solvent decomposition. [Hdma]2·[Hgua]·[NH4]·[ZnFeIIIF5(amtetraz)2]2 (3), [Hdma]2·[Zn1.6FeII0.4FeIIIF6(amtetraz)3] (4), and [Hdma]·[Zn4F5(amtetraz)4] (5) are considered as Class II hybrids in which the (amtetraz)− anions are strongly linked to divalent metal cations via N–M bonds. In 3, ∞{[NH4]·[ZnFeIIIF5(amtetraz)2]2} layers are separated by [Hdma]+ and [Hgua]+ cations. 4 and 5 exhibit three-dimensional (3D) hybrid networks that contain small cavities where [Hdma]+ cations are inserted. A porous 3D metal–organic framework intermediate is evidenced from the thermogravimetric analysis and X-ray thermodiffraction of 5.