| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Gomes, Clara
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023A Polymorph of Dipeptide Halide Glycyl-L-Alanine Hydroiodide Monohydrate: Crystal Structure, Optical Second Harmonic Generation, Piezoelectricity and Pyroelectricitycitations
- 2023Reversible Single-Crystal-to-Single-Crystal Transformations in a salEen Fe(III) Spin Crossover Spongecitations
- 2019Cu(II) complexes derived from N-carboxymethyl and N-carboxyethyl amino acids as catalysts for asymmetric oxidative coupling of 2-naphtholcitations
- 2018New phenyl-nickel complexes of bulky 2-iminopyrrolyl chelatescitations
- 2015Exploring the influence of steric hindrance and electronic nature of substituents in the supramolecular arrangements of 5-(substituted phenyl)-2-formylpyrrolescitations
- 2014Copper(ii) complexes of bis(aryl-imino)acenaphthene ligandscitations
- 2011New tetradentate N,N,N,N-chelating α-diimine ligands and their corresponding zinc and nickel complexescitations
- 2009Trans-Chlorido(phen-yl)bis-(triphenyl-phosphine)nickel(II) and its 1:1 cocrystal with chloridobis(triphenyl-phosphine)nickel(I)citations
Places of action
| Organizations | Location | People |
|---|
article
Reversible Single-Crystal-to-Single-Crystal Transformations in a salEen Fe(III) Spin Crossover Sponge
Abstract
<p>The storage of guest molecules in nonporous single crystals is an important development in the field of smart materials. We describe the synthesis and characterization of the new spin crossover Fe(III) compound [Fe(3-Br,5-Cl-salEen)<sub>2</sub>]BPh<sub>4</sub>·CH<sub>3</sub>CN·H<sub>2</sub>O (salEen = N-ethyl-N-(2-aminoethyl)salicylaldiminate) and its reversible single-crystal-to-single-crystal transformation upon desolvation and resolvation of the crystals. This process affects the magnetic behavior of the compound while the desolvation of single crystals is made in several steps. The magnetic profiles of the cooling/heating routines are never coincident until the compound reaches the high-spin state after complete desolvation of the single crystals. This is further reflected in temperature-dependent Raman profiles where desolvated and high spin state spectra match after the temperature cycle. Kinetic studies gave insights on the desolvation/resolvation dynamics with the new Fe(III) compound behaving as a spin crossover sponge.</p>