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Michalchuk, Adam
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Publications (9/9 displayed)
- 2024Tuning energetic properties through co-crystallisation – a high-pressure experimental and computational study of nitrotriazolonecitations
- 2023High-pressure Structural Studies and Pressure-induced Sensitisation of 3,4,5-trinitro-1H-pyrazolecitations
- 2023Shared metadata for data-centric materials sciencecitations
- 2022Dispersive x-ray absorption spectroscopy for time-resolved in situ monitoring of mechanochemical reactionscitations
- 2022Unintended rate enhancement in mechanochemical kinetics by using poly(methyl methacrylate) jarscitations
- 2022Plastically bendable organic crystals for monolithic and hybrid micro‐optical circuitscitations
- 2021Monitoring mechanochemical processes in situ and in real timecitations
- 2021High-pressure reversibility in a plastically flexible coordination polymer crystalcitations
- 2020A Mechanistic Perspective on Plastically Flexible Coordination Polymerscitations
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article
Unintended rate enhancement in mechanochemical kinetics by using poly(methyl methacrylate) jars
Abstract
Time-resolved in situ (TRIS) X-ray diffraction has changed how mechanochemical transformations are studied but requires the use of X-ray transparent jars often made from poly(methyl methacrylate) (PMMA). However, using PMMA jars can alter the apparent kinetics of mechanochemical polymorphism by an order of magnitude, questioning the interpretability of established TRIS methods. Our results suggest that rate enhancement in PMMA jars may not be dominated by chemical effects of the polymer, but rather a result of different equilibrium temperatures within the jar. These features must be better understood before control over mechanochemical reactions can be achieved.