| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Cordes, David Bradford
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2024NaLiFe(C2O4)2 : a polyanionic Li/Na-ion battery cathode exhibiting cationic and anionic redoxcitations
- 2024Synthesis, characterization, X-ray Crystallography, Photoluminescence property and DNA binding activity of Co(II) and Ni(II) complexes of a pyrazole containing Schiff-base ligandcitations
- 2024NaLiFe(C 2 O 4 ) 2 :a polyanionic Li/Na-ion battery cathode exhibiting cationic and anionic redoxcitations
- 2023Manipulation of structure and optoelectronic properties through bromine inclusion in a layered lead bromide perovskitecitations
- 2023Synthesis, spectroscopy and structural elucidation of two new CoII and NiII complexes of pyrazole derived heterocyclic Schiff base ligand as potential anticancer and photocatalytic agents
- 2022Synthesis, structure and tunability of zero dimensional organic-inorganic metal halides utilising the m-xylylenediammonium cation: MXD2PbI6, MXDBiI5, and MXD3Bi2Br12·2H2Ocitations
- 2022A two-dimensional manganese-containing coordination polymer for efficient catalysis of the oxygen evolutioncitations
- 2022Structure determination and Hirshfeld surface analysis of new cocrystal and salt forms of 5-aminotetrazole with hydroxy- and nitro-substituted carboxylic acidscitations
- 2022Cadmium(II) Schiff base complex containing 5-fluoroisatin moietycitations
- 2021A simplified extractive metallurgy exercise to demonstrate selective extraction of coppercitations
- 2020A simplified extractive metallurgy exercise to demonstrate selective extraction of coppercitations
- 2019Stable 6H organic-inorganic hybrid lead perovskite and competitive formation of 6H and 3C perovskite structure with mixed A cationscitations
- 2019A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Unitscitations
- 2019A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and releasecitations
- 2018A study of through-space and through-bond JPP coupling in a rigid nonsymmetrical bis(phosphine) and its metal complexescitations
- 2018Synthesis, characterization and antimicrobial activities of Co(III) and Ni(II) complexes with 5-methyl-3-formylpyrazole-N(4)-dihexylthiosemicarbazone (HMPzNHex2)citations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groups:a combined experimental and theoretical studycitations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groups : a combined experimental and theoretical studycitations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groupscitations
- 2016Synthesis and characterization of green-to-yellow emissive Ir(III) complexes of pyridylbenzothiadiazine ligandcitations
- 2016Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligandscitations
- 2016Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligandscitations
- 2016Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2016Synthesis, properties and Light-Emitting Electrochemical Cell (LEEC) device fabrication of cationic Ir(III) complexes bearing electron-withdrawing groups on the cyclometallating ligandscitations
- 2016Synthesis, properties and Light-Emitting Electrochemical Cell (LEEC) device fabrication of cationic Ir(III) complexes bearing electron-withdrawing groups on the cyclometallating ligandscitations
- 2015Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2015Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2012Reactivity of dipyrimidyldiselenides with [M(PPh3)(4)] and 2-pyrimidylchalcogenolates with [MCl2(diphosphine)] (M = Pd or Pt)citations
- 2012Nanoporous Carbohydrate Metal-Organic Frameworkscitations
Places of action
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article
Synthesis, structure and tunability of zero dimensional organic-inorganic metal halides utilising the m-xylylenediammonium cation: MXD2PbI6, MXDBiI5, and MXD3Bi2Br12·2H2O
Abstract
JLP thanks the University of St Andrews for funding and the Carnegie Trust for a Research Incentive Grant (RIG008653). We thank EPSRC for funding (EP/T019298/1 and EP/R023751/1). ; Over the past decade, the efficiency of photovoltaic devices based on CH3NH3PbI3 have dramatically increased. This has driven research efforts in all areas, from the discovery of materials to film processing to long-term device stability studies. Here, we report the synthesis and structure of three new “zero dimensional” organic–inorganic metal halides which use the meta-xylylenediammonium (MXD) cation: MXD2PbI6, MXDBiI5, and (MXD)3Bi2Br12·2H2O. The different structures of the new materials lead to compounds with a range of band gaps with MXDBiI5 having the lowest at 2.15 eV. We have explored the tunabilty of MXDBiI5 through halide substitution by preparing a series of samples with composition MXDBiI5–xBrx and determined the halide content using energy dispersive X-ray spectroscopy. A large range of solid solution is obtained in MXDBiI5–xBrx, resulting in the formation of single-phase materials for bromine contents from x = 0 to 3.71 (iodine contents from 1.29 to 5). This highlights the fact that zero-dimensional organic–inorganic halides are highly tunable, in a similar manner to the higher-dimensional perovskite counterparts. Such new materials open up the opportunity for further studies of the physics and optoelectronic properties of these materials. ; Peer reviewed