| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Mishra, Shashank
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Surface segregation in the AgAuCuPdPt high entropy alloy: insights from molecular simulationscitations
- 2021Vapor Phase Synthesis of SnS Facilitated by Ligand-Driven “Launch Vehicle” Effect in Tin Precursorscitations
- 2021Asymmetry-Induced Redistribution in Sn(IV)–Ti(IV) Hetero-Bimetallic Alkoxide Precursors and Its Impact on Thin-Film Deposition by Metal–Organic Chemical Vapor Depositioncitations
- 2020Optimum in the thermoelectric efficiency of nanostructured Nb-doped TiO 2 ceramics: from polarons to Nb–Nb dimerscitations
- 2020Optimum in the thermoelectric efficiency of nanostructured Nb-doped TiO 2 ceramics: from polarons to Nb–Nb dimerscitations
- 2020Effect of High Pressure Spark Plasma Sintering on the Densification of a Nb-Doped TiO2 Nanopowdercitations
- 2020Effect of High Pressure Spark Plasma Sintering on the Densification of a Nb-Doped TiO2 Nanopowdercitations
- 2018Chemical Vapor Deposition of Al 13 Fe 4 Highly Selective Catalytic Films for the Semi-Hydrogenation of Acetylenecitations
- 2017Chemical Vapor Deposition of Al 13 Fe 4 Highly Selective Catalytic Films for the Semi-Hydrogenation of Acetylenecitations
- 2015A convenient and quantitative route to Sn(IV)-M M = Ti(IV), Nb(V), Ta(V) heterobimetallic precursors for dense mixed-metal oxide ceramicscitations
Places of action
| Organizations | Location | People |
|---|
article
Asymmetry-Induced Redistribution in Sn(IV)–Ti(IV) Hetero-Bimetallic Alkoxide Precursors and Its Impact on Thin-Film Deposition by Metal–Organic Chemical Vapor Deposition
Abstract
With an aim to enhance the stability and volatility of the heterometallic derivative [SnCl4(µ-OEt)2Ti(OEt)2(HOEt)2] (A), obtained conveniently and quantitatively as a simple adduct formula from the equivalent reaction of commercially available SnCl4 and Ti(OEt)4 in toluene/ethanol, its modification with 2,2,6,6-heptane-3,5-dione (thdH) is reported. The modified precursor [SnCl4(µ-OEt)2Ti(thd)(OEt)(HOEt)] (1), obtained from equimolar reaction of A and thdH, is stable at room temperature but rearranges on heating into A and [SnCl4(µ-OEt)2Ti(thd)2] (2), as confirmed by the vapor pressure measurements and DFT calculations. The heterometallic 2 can be obtained in excellent yield from the reaction of A and thdH in 1:2 molar ratio and is stable in solid and solution phase up to 200 °C. However, the asymmetric nature of its structure consisting of fragments of titanium β-diketonate and tin chloride connected by bridging ethoxo groups, leads to breakdown into two homometallic components in gas phase, leading to deposition of tin-rich metal oxide films on the substrate.