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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Plank, Harald
Graz University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2024Nanoscale, surface-confined phase separation by electron beam induced oxidationcitations
- 2024A Review on Direct-Write Nanoprinting of Functional 3D Structures with Focused Electron Beamscitations
- 2023Thermally-triggered multi-shape-memory behavior of binary blends of cross-linked EPDM with various thermoplastic polyethylenes and their potential applications as temperature indicatorscitations
- 2023Spectral Tuning of Plasmonic Activity in 3D Nanostructures via High-Precision Nano-Printingcitations
- 2023Pillar Growth by Focused Electron Beam-Induced Deposition Using a Bimetallic Precursor as Model Systemcitations
- 2022Vanadium and Manganese Carbonyls as Precursors in Electron-Induced and Thermal Deposition Processes
- 2022A study on the correlation between micro and magnetic domain structure of Cu52Ni34Fe14 spinodal alloyscitations
- 2022Direct-Write 3D Nanoprinting of High-Resolution Magnetic Force Microscopy Nanoprobes
- 2022Precursors for Direct-Write Nanofabrication with Electrons
- 2022Localized Direct Material Removal and Deposition by Nanoscale Field Emission Scanning Probescitations
- 2022Focused Ion Beam vs Focused Electron Beam Deposition of Cobalt Silicide Nanostructures Using Single-Source Precursorscitations
- 2020Cellulose metal sulfide based nanocomposite thin films
- 2019Focused Electron Beam Induced Deposition Synthesis of 3D Photonic and Magnetic Nanoresonatorscitations
- 2019In situ real-time annealing of ultrathin vertical Fe nanowires grown by focused electron beam induced depositioncitations
- 2019Multi-layered nanoscale cellulose/CuInS2 sandwich type thin filmscitations
- 2019Analyzing the Nanogranularity of Focused-Electron-Beam-Induced-Deposited Materials by Electron Tomographycitations
- 2018Thin Films from Acetylated Lignin
- 2017How Bound and Free Fatty Acids in Cellulose Films Impact Nonspecific Protein Adsorptioncitations
- 2017How Bound and Free Fatty Acids in Cellulose Films Impact Nonspecific Protein Adsorptioncitations
- 2016Enzymes as Biodevelopers for Nano- And Micropatterned Bicomponent Biopolymer Thin Films.citations
- 2014The nanoscale implications of a molecular gas beam during electron beam induced depositioncitations
- 2014Purification of Nanoscale Electron-Beam-Induced Platinum Deposits via a Pulsed Laser-Induced Oxidation Reactioncitations
- 2014A combined approach to predict spatial temperature evolution and its consequences during FIB processing of soft mattercitations
- 2013Chemical degradation and morphological instabilities during focused ion beam prototyping of polymerscitations
- 2013Variable tunneling barriers in FEBID based PtC metal-matrix nanocomposites as a transducing element for humidity sensingcitations
- 2012Direct electroplating of copper on tantalum from ionic liquids in high vacuum: Origin of the tantalum oxide layercitations
- 2012Direct-on-barrier copper electroplating on ruthenium from the ionic liquid 1-ethyl-3-methylimidazolium dicyanamidecitations
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article
How Bound and Free Fatty Acids in Cellulose Films Impact Nonspecific Protein Adsorption
Abstract
The effect of fatty acids and fatty acid esters to impair nonspecific protein adsorption on cellulose thin films is investigated. Thin films are prepared by blending trimethylsilyl cellulose solutions with either cellulose stearoyl ester or stearic acid at various ratios. After film formation by spin coating, the trimethylsilyl cellulose fraction of the films is converted to cellulose by exposure to HCl vapors. The morphologies and surface roughness of the blends were examined by atomic force microscopy revealing different feature shapes and sizes depending on the blend ratios. Nonspecific protein adsorption at the example of bovine serum albumin toward the blend thin films was tested by means of surface plasmon resonance spectroscopy in real-time. Incorporation of stearic acid into the cellulose leads to highly protein repellent surfaces regardless of the amount added. The stearic acid acts as a sacrificial compound that builds a complex with bovine serum albumin thereby inhibiting protein adsorption. For the blends where stearoyl ester is added to the cellulose films, the cellulose:cellulose stearoyl ester ratios of 3:1 and 1:1 lead to much lower nonspecific protein adsorption compared to pure cellulose, whereas for the other ratios, adsorption increases. Supplementary results were obtained from atomic force microscopy experiments performed in liquid during exposure to protein solution and surface free energy determinations.