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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Khakalo, Alexey
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Biodegradable Cellulose Nanocomposite Substrate for Recyclable Flexible Printed Electronicscitations
- 2022Nanocellulose Removes the Need for Chemical Crosslinking in Tannin-Based Rigid Foams and Enhances Their Strength and Fire Retardancycitations
- 2021Manufacture of all-wood sawdust-based particle board using ionic liquid-facilitated fusion processcitations
- 2021Rheological behavior of high consistency enzymatically fibrillated cellulose suspensionscitations
- 2020Wood based materials with ionic liquid fusion
- 2019Anti-oxidative and UV-absorbing biohybrid film of cellulose nanofibrils and tannin extractcitations
- 2018The effect of oxyalkylation and application of polymer dispersions on the thermoformability and extensibility of papercitations
- 2018Protein-mediated interfacial adhesion in composites of cellulose nanofibrils and polylactidecitations
- 2017Layer-by-layer assembled hydrophobic coatings for cellulose nanofibril films and textiles, made of polylysine and natural wax particles
- 2017Protein Adsorption Tailors the Surface Energies and Compatibility between Polylactide and Cellulose Nanofibrilscitations
- 2017Advanced Structures and Compositions for 3D Forming of Cellulosic Fiberscitations
- 2017Advanced Structures and Compositions for 3D Forming of Cellulosic Fibers:Dissertation
- 2016Effect of polyurethane addition on the strength, extensibility and 3D formability of paper and board
- 2016Combined mechanical and chemical modifications towards super-stretchable paper-based materials
Places of action
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article
Protein Adsorption Tailors the Surface Energies and Compatibility between Polylactide and Cellulose Nanofibrils
Abstract
<p>The state of dispersion and the interactions between a polymer and a filler in a nanocomposite crucially define its properties and performance. The affinity of polylactide (PLA) with vegetable and animal proteins (casein, gelatin, soy protein isolate, and hydrolysate) is investigated and their role as eco-friendly dispersants and compatibilizers of cellulose nanofibrils (CNF) is elucidated. The affinity of the proteins with PLA is determined by using sensograms acquired by electroacoustic (quartz crystal microgravimetry) and optical (surface plasmon resonance) techniques. The surface energy of PLA increases upon protein adsorption while the opposite effect is observed for CNF, under identical experimental conditions. A significant improvement in the thermodynamic work of adhesion for PLA/CNF systems is predicted by application of the denatured proteins at low concentrations (∼20% and ∼15% enhancement with soy protein and casein at pH 3 and pH 8, respectively). We offer a robust method to screen denatured proteins and to tailor the wettability and material compatibility in the synthesis of bionanocomposites based on CNF and PLA.</p>