| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Skelton, Jonathan M.
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024Electronic transport and the thermoelectric properties of donor-doped SrTiO3citations
- 2024Composition-dependent morphologies of CeO2 nanoparticles in the presence of Co-adsorbed H2O and CO2citations
- 2024Composition-dependent morphologies of CeO 2 nanoparticles in the presence of Co-adsorbed H 2 O and CO 2 : a density functional theory studycitations
- 2023Thermoelectric properties of Pnma and R3m GeS and GeSecitations
- 2023A Low‐Temperature Synthetic Route Toward a High‐Entropy 2D Hexernary Transition Metal Dichalcogenide for Hydrogen Evolution Electrocatalysiscitations
- 2023A Low‐Temperature Synthetic Route Toward a High‐Entropy 2D Hexernary Transition Metal Dichalcogenide for Hydrogen Evolution Electrocatalysiscitations
- 2023Breathing Behaviour Modification of Gallium MIL‐53 Metal–Organic Frameworks Induced by the Bridging Framework Inorganic Anioncitations
- 2023Synthetic Strategies toward High Entropy Materials: Atoms-to-Lattices for Maximum Disordercitations
- 2023Enhanced Thermoelectric Performance of Tin(II) Sulfide Thin Films Prepared by Aerosol Assisted Chemical Vapor Depositioncitations
- 2020Polymorph exploration of bismuth stannate using first-principles phonon mode mappingcitations
- 2020Lattice dynamics of Pnma Sn(S1-xSex) solid solutions: energetics, phonon spectra and thermal transportcitations
- 2020Assessment of dynamic structural instabilities across 24 cubic inorganic halide perovskitescitations
- 2020Watching Photochemistry Happencitations
- 2019Thermodynamics, Electronic Structure, and Vibrational Properties of Sn n(S 1- xSe x) m Solid Solutions for Energy Applicationscitations
- 2019Room Temperature Metallic Conductivity in a Metal–Organic Framework Induced by Oxidationcitations
- 2019Thermodynamics, Electronic Structure, and Vibrational Properties of Sn n (S 1– x Se x) m Solid Solutions for Energy Applicationscitations
- 2019Photocrystallographic studies on transition metal nitrito metastable linkage isomers: manipulating the metastable statecitations
- 2018Acoustic phonon lifetimes limit thermal transport in methylammonium lead iodidecitations
- 2018Understanding the fast phase-change mechanism of tetrahedrally bonded Cu 2 GeTe 3 :Comprehensive analyses of electronic structure and transport phenomenacitations
- 2018Understanding the fast phase-change mechanism of tetrahedrally bonded Cu2GeTe3citations
- 2018Hydrogen Bonding versus Entropycitations
- 2017Chemical and Lattice Stability of the Tin Sulfidescitations
- 2016Phonon anharmonicity, lifetimes, and thermal transport in CH 3 NH 3 PbI 3 from many-body perturbation theorycitations
- 2016Phonon anharmonicity, lifetimes, and thermal transport in CH3NH3PbI3 from many-body perturbation theorycitations
- 2016Observation of a re-entrant phase transition in the molecular complex tris(μ2-3,5-diisopropyl-1,2,4-triazolato-κ2N1:N2)trigold(I) under high pressurecitations
- 2016A general forcefield for accurate phonon properties of metal-organic frameworkscitations
- 2016Band alignments, valence bands, and core levels in the tin sulfides SnS, SnS2, and Sn2S3citations
- 2016Computational materials design of crystalline solidscitations
- 2015Influence of the exchange-correlation functional on the quasi-harmonic lattice dynamics of II-VI semiconductorscitations
- 2014Atomistic origin of the enhanced crystallization speed and n-type conductivity in Bi-doped Ge-Sb-Te phase-change materialscitations
Places of action
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article
Photocrystallographic studies on transition metal nitrito metastable linkage isomers: manipulating the metastable state
Abstract
The design of solid-state materials whose properties and functions can be manipulated in a controlled manner by the application of light is an important objective in modern materials chemistry. When the material changes property or function, it is helpful if a simple measurable response, such as a change in color, can be detected. Potential applications for such materials are wide ranging, from data storage to smart windows. With the growing emphasis on solid-state materials that have two or more accessible energy states and which exhibit bistability, attention has turned to transition metal complexes that contain ambidentate ligands that can switch between linkage isomeric forms when activated by light. Suitable ligands that show promise in this area include nitrosyls, nitro groups, and coordinated sulfur dioxide molecules, each of which can coordinate to a metal center in more than one bonding mode. A nitrosyl normally coordinates through its N atom (η1-NO) but when photoactivated can undergo isomerism and coordinate through its O atom (η1-ON). At a molecular level, converting between these two configurations can act as an “on/off” switch. The analysis of such materials has been aided by the development of photocrystallographic techniques, which allow the full three-dimensional structure of a single crystal of a complex, under photoactivation, to be determined, when it is in either a metastable or short-lived excited state. The technique effectively brings the dimension of “time” to the crystallographic experiment and brings us closer to being able to watch solid-state processes occur in real time. In this Account, we highlight the advances made in photocrystallography for studying solid-state, photoactivated linkage isomerism and describe the factors that favor the switching process and which allow complete switching between isomers. We demonstrate that control of temperature is key to achieving either a metastable state or an excited state with a specific lifetime. We draw our conclusions from published work ...