| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ferrer, Pilar
Diamond Light Source
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Volcanic Eruption in the Nanoworld: Efficient Oxygen Exchange at the Si/SnO<sub>2</sub> Interface
- 2024The Role of Salt Concentration in Stabilizing Charged Ni-Rich Cathode Interfaces in Li-ion Batteries
- 2022Identifying chemical and physical changes in wide-gap semiconductors using real-time and near ambient-pressure XPS ; ENEngelskEnglishIdentifying chemical and physical changes in wide-gap semiconductors using real-time and near ambient-pressure XPScitations
- 2022Identifying chemical and physical changes in wide-gap semiconductors using real-time and near ambient-pressure XPScitations
- 2021Influence of the synthesis parameters on the proton exchange membrane fuel cells performance of Fe–N–C aerogel catalystscitations
- 2020Understanding metal organic chemical vapour deposition of monolayer WS2: the enhancing role of Au substrate for simple organosulfur precursors.
- 2020Understanding metal organic chemical vapour deposition of monolayer WS<sub>2</sub>: the enhancing role of Au substrate for simple organosulfur precursors.
- 2014Synthesis and crystal structure of the novel metal organic framework Zn(C3H5NO2S)2citations
- 2012A flow-through reaction cell forin situX-ray diffraction and absorption studies of heterogeneous powder–liquid reactions and phase transformationscitations
Places of action
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article
Synthesis and crystal structure of the novel metal organic framework Zn(C3H5NO2S)2
Abstract
<jats:p>The crystal structure of the novel metal organic framework (MOF) Zn(C<jats:sub>3</jats:sub>H<jats:sub>5</jats:sub>NO<jats:sub>2</jats:sub>S)<jats:sub>2</jats:sub> is described. This MOF can serve as a model for active sites in metalloproteins, on diverse activities such as structural or catalytic functions. Each half of the amino acid act as a bidentate ligand to one Zn and as a monodentate ligand to another Zn, while the disulphide bond presents an important structural function, stabilizing the crystal packing. The structure has been obtained <jats:italic>ab initio</jats:italic> from synchrotron X-ray powder diffraction data. The compound crystallizes in the orthorhombic system (space group <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub>2<jats:sub>1</jats:sub>2<jats:sub>1</jats:sub>), with <jats:italic>a</jats:italic> = 20.0906(7), <jats:italic>b</jats:italic> = 9.5842(3), <jats:italic>c</jats:italic> = 5.018 89(13), and <jats:italic>V</jats:italic> = 966.40(5) Å<jats:sup>3</jats:sup>, with <jats:italic>Z</jats:italic> = 4. The structure was determined using a direct space approach, by means of the Monte Carlo technique, followed by Rietveld refinement.</jats:p>