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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Szala, M.
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article
Self-sustaining high-temperature synthesis of carbon-encapsulated magnetic nanoparticles from organic and inorganic metal precursors
Abstract
<p>A systematic study on the synthesis of carbon-encapsulated magnetic nanoparticles by self-sustaining high-temperature synthesis (SHS) is presented. The SHS was carried out using NaN<sub>3</sub> as a reducer; and poly(tetrafluoroethene) (C<sub>2</sub>F<sub>4</sub>)n, hexachloroethane (C<sub>2</sub>Cl<sub>6</sub>) and hexachlorobenzene (C<sub>6</sub>Cl<sub>6</sub>) as three various oxidizers. The effect of metal precursor, (Fe(CO)<sub>5</sub> or K<sub>3</sub>[Fe(CN)<sub>6</sub>]) on the yield, reaction heat, morphology, structure and magnetic properties of the products was investigated. The highest product yield with best magnetic characteristics was obtained from the organometallic iron precursor and C<sub>2</sub>Cl<sub>6</sub> oxidizer.</p>