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| Naji, M. |
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Vassilyeva, O. Y.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2016Divalent manganese, cobalt and nickel chloride complexes with neutral N2- and N3-based ligands derived from 2-pyridinecarbaldehyde: Synthesis, structural features and spectroscopic studiescitations
- 2015Hybrid organic-inorganic chlorozincate and a molecular zinc complex involving the in situ formed imidazo[1,5-a]pyridinium cation: Serendipitous oxidative cyclization, structures and photophysical propertiescitations
- 2014Unusual cocrystals made of a Schiff base metal complex and an organic molecule - Close-packing vs. hydrogen bond interactionscitations
- 2009Cu/Cd heterometallic solids with the motif (H2dea = diethanolamine): Exchange interactions through hydrogen bondingcitations
- 2003A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcoholcitations
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article
A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol
Abstract
The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.