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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Halsall, Mp
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Topics
Publications (8/8 displayed)
- 2021Passivation of thermally-induced defects with hydrogen in float-zone siliconcitations
- 2018Graphene oxide films for field effect surface passivation of silicon for solar cellscitations
- 2018Deep-level analysis of passivation of transition metal impurities in siliconcitations
- 2013Donor ionization in size controlled silicon nanocrystals: The transition from defect passivation to free electron generationcitations
- 2013Size limit on the phosphorous doped silicon nanocrystals for dopant activationcitations
- 2010Formation of Si-nanocrystals in SiO2 via ion implantation and rapid thermal processingcitations
- 2010Structure and luminescence of rare earth-doped silicon oxides studied through their X-ray absorption near edge structure and X-ray excited optical luminescencecitations
- 2001Investigation into the deformation of carbon nanotubes and their composites through the use of Raman spectroscopycitations
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article
Investigation into the deformation of carbon nanotubes and their composites through the use of Raman spectroscopy
Abstract
The deformation micromechanics of single-walled carbon nanotube (SWNT) and multi-walled carbon nanotube (MWNT) particulate nanocomposites has been studied using Raman spectroscopy. SWNTs prepared by two different methods (pulsed-laser and arc-discharge) and MWNTs have been used as reinforcement for a polymer matrix nanocomposite. The carbon nanotubes exhibit well-defined Raman peaks and Raman spectroscopy has been used to follow their deformation. SWNTs have been deformed with hydrostatic pressure in a diamond anvil pressure cell and has been found that the G′ peak position shifts to a higher wavenumber with hydrostatic compression. It has been found that for all nanocomposites samples deformed, the G′ Raman band shifts to a lower wavenumber upon application of a tensile stress indicating stress transfer from the matrix to the nanotubes and hence reinforcement by the nanotubes. The behaviour has been compared with that of high-modulus carbon fibres and has been modelled using orientation factors suggested initially by Cox. In this way it has been possible to demonstrate that the effective modulus of SWNTs dispersed in a composite could be over 1 TPa and that of the MWNTs about 0.3 TPa.