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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Besana, Sonja
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article
Thermodynamic investigations in the lanthanum-cadmium system
Abstract
An isopiestic vapor pressure method was developed which allows vapor pressure measurements in systems containing elements that are air and/or moisture sensitive. With this method, cadmium vapor pressures were determined for the intermetallic compound La13Cd58 and the neighboring two-phase field with LaCd2 between about 750 and 1020 K. From these, activities and partial molar enthalpies were derived, and integral Gibbs energies of formation were obtained by a Gibbs-Duhem integration. It was found that the compound La13Cd58 shows some non-stoichiometry extending between about 79 and 81.5 at.% Cd. The enthalpy of formation of La13Cd58 was determined by a calorimetric method; it was found to be ?H298=-32.0‘2.0 kJ mol -1. Œ 2003 Elsevier B.V. All rights reserved.