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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zygadło-Monikowska, Ewa
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2020Magnesium tetraorganyl derivatives of group 13 metals as intermediate products in the synthesis of group 13 metal alkyls and arylscitations
- 2017Synthesis and properties of new carboxyborate lithium salts as electrolytes for lithium-ion batteriescitations
- 2015Synthesis and characterization of lithium-salt complexes with difluoroalkoxyborates for application as lithium electrolytescitations
- 2015Study of ageing effects in polymer-in-salt electrolytes based on poly(acrylonitrile-co-butyl acrylate) and lithium saltscitations
- 2014Lithium electrolytes based on modified imidazolium ionic liquidscitations
- 2013Benzoxaborolate ligands in group 13 metal complexescitations
- 2011Synthesis and characterization of new trifluoroalkoxyborates lithium salts of ionic liquid propertiescitations
- 2008Influence of plasticizer type on the properties of polymer electrolytes based on chitosancitations
- 2004Polymer-in-salt electrolytes based on acrylonitrile/butyl acrylate copolymers and lithium saltscitations
- 2003Effects of inhomogeneity on ionic conductivity and relaxations in PEO and PEO–salt complexescitations
- 2000The effect of solvent and proton donor type on the conductivity and physico-chemical properties of poly(vinylidene fluoride)-based proton-conducting gel electrolytescitations
Places of action
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article
Effects of inhomogeneity on ionic conductivity and relaxations in PEO and PEO–salt complexes
Abstract
Electrical properties of purified poly(ethylene oxide)-PEO and PEO with dissolved lithium salts, PEO10:LiCF3SO3 and PEO10:LiN(CF3SO2)2, were investigated by impedance spectroscopy. Changes of the impedance spectra during crystallization and melting were recorded. Semicrystalline polymer films exhibited frequency dependence of conductivity with two limiting values of conductivity at low and at high frequency. It was concomitant with dispersion of the electric permittivity exhibiting the low-frequency values of the order of 200. In the case of PEO with dissolved salt, when the film was quasi-amorphous, the electric permittivity also exhibited pronounced dispersion, which was probably due to the presence of crystalline PEO–salt complexes. The dielectric relaxation caused by rearrangement of dipoles in PEO chain was observed at low temperatures and high frequencies.