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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hansen, Karin Vels
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Topics
Publications (21/21 displayed)
- 2021Short-term strong cathodic polarization of Ni/YSZ and Pt/YSZ
- 2019Influence of sintering profile on the microstructure and electronic transport properties of Sr(Ti,Nb)O3 tapes for solid oxide cell applications
- 2019Probe electrode study of cathodically polarized PtIr-YSZ interfacescitations
- 2017Dynamic and Impure Perovskite Structured Metal Oxide Surfacescitations
- 2016Effects of strong cathodic polarization of the Ni-YSZ interfacecitations
- 2016New Hypothesis for SOFC Ceramic Oxygen Electrode Mechanismscitations
- 2015Environmental TEM study of the dynamic nanoscaled morphology of NiO/YSZ during reductioncitations
- 2015Need for In Operando Characterization of Electrochemical Interface Features
- 2015Dynamic behavior of impurities and native components in model LSM microelectrodes on YSZcitations
- 2014NiO/YSZ Reduction for SOFC/SOEC Studied In Situ by Environmental Transmission Electron Microscopycitations
- 2014In situ surface reduction of a NiO-YSZ-alumina composite using scanning probe microscopycitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La0.75Sr0.25)0.95MnO3 on YSZcitations
- 2013Electrochemical reduction of NiO in a composite electrodecitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La 0.75 Sr 0.25 ) 0.95 MnO 3 on YSZcitations
- 2012Composite Sr- and V-doped LaCrO 3 /YSZ sensor electrode operating at low oxygen levelscitations
- 2012Fundamental Material Properties Underlying Solid Oxide Electrochemistry
- 2012Composite Sr- and V-doped LaCrO3/YSZ sensor electrode operating at low oxygen levelscitations
- 2010Quantitative data analysis methods for 3D microstructure characterization of Solid Oxide Cells
- 2010High Performance Fe-Co Based SOFC Cathodescitations
- 2008Effects of trace elements at the Ni/ScYSZ interface in a model solid oxide fuel cell anodecitations
- 2001Microstructural and chemical changes at the Ni/YSZ interfacecitations
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article
Microstructural and chemical changes at the Ni/YSZ interface
Abstract
A bent nickel wire was pressed against a yttria-stabilised zirconia (YSZ) surface, creating a small contact area. The Ni/YSZ interface was investigated and characteristic microstructures were found to develop during 200-300 h heat treatment at 1000 degreesC in 97% H-2/3% H2O with and without polarisation. A ridge of impurities up to 1.6 mum high was seen to develop along the Ni/YSZ/H-2 boundary. The impurity phase can be characterised as an alkali silicate phase containing Mn, Na, Ti, Mg, K, Al and Si. Most of these elements seem to be coming from impurities in the nickel. The initially flat contact area on the YSZ developed a hill and valley structure with an amplitude of 100 nm. The nickel wires showed negative imprints of the YSZ structures. (C) 2001 Elsevier Science B.V. All rights reserved.