| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Dubois, Philippe
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2011Novel polyesteramide-based di- and triblock copolymerscitations
- 2008Controlled synthesis of amphiphilic block copolymers based on polyester and poly(amino methacrylate)citations
- 2008Designing polylactide/clay nanocomposites for textile applicationscitations
- 2008Undecyltin trichloride grafted onto cross-linked polystyrenecitations
- 2008CH-π interactions as the driving force for silicone-based nanocomposites with exceptional propertiescitations
- 2007(Plasticized) Polylactide/clay nanocomposite textilecitations
- 2007Polylactide compositions. Part 1citations
- 2007Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radical polymerizationcitations
- 2006Copper-based supported catalysts for the atom transfer radical polymerization of methyl methacrylatecitations
- 2005Polylactide/montmorillonite nanocompositescitations
- 2005(Plasticized) polylactide/(organo-)clay nanocomposites by in situ intercalative polymerizationcitations
- 2005Nickel-catalyzed supported ATRP of methyl methacrylate using cross-linked polystyrene triphenylphosphine as ligandcitations
- 2004End-grained wood-polyurethane composites, 1 synthesis, morphology and characterizationcitations
- 2004Synthesis of melt-stable and semi-crystalline poly(1,4-dioxan-2-one) by ring-opening (co)polymerisation of 1,4-dioxan-2-one with different lactonescitations
- 2004Supported nickel bromide catalyst for Atom Transfer Radical Polymerization (ATRP) of methyl methacrylatecitations
- 2004Diblock copolymers based on 1,4-dioxan-2-one and ε-caprolactonecitations
- 2003Intercalative polymerization of cyclic esters in layered silicatescitations
- 2003Biodegradation of poly(ε-caprolactone)/starch blends and composites in composting and culture environmentscitations
- 2003Exfoliated polylactide/clay nanocomposites by in-situ coordination-insertion polymerizationcitations
- 2002New nanocomposite materials based on plasticized poly(L-lactide) and organo-modified montmorillonitescitations
- 2001Poly(ϵ-caprolactone) layered silicate nanocompositescitations
- 2001Some thermodynamic, kinetic, and mechanistic aspects of the ring-opening polymerization of 1,4-dioxan-2-one initiated by Al(OiPr)3 in bulkcitations
- 2001Mechanisms and kinetics of thermal degradation of poly(ε-caprolactone)citations
- 2000New developments on the ring opening polymerisation of polylactidecitations
Places of action
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article
New nanocomposite materials based on plasticized poly(L-lactide) and organo-modified montmorillonites
Abstract
<p>Plasticized poly(L-lactide) (PLA) based nanocomposites were prepared by melt blending of the matrix with 20 wt% of poly(ethyleneglycol) 1000 (PEG 1000) and different amounts of montmorillonite, organo-modified or not. The intercalation of the polymer chains between the aluminosilicates layers and morphological structure of the filled PLAs were analysed by wide-angle X-ray scattering (WAXS). Thermogravimetric analyses (TGA) and differential scanning calorimetry (DSC) were performed to study the thermal behaviour of the prepared composites. At constant filler level, it appears that from all the clays studied, the montmorillonite organo-modified by bis-(2-hydroxyethyl)methyl (hydrogenated tallowalkyl) ammonium cations brings the greater effect in terms of thermal stability. Increasing the amount of clay allows to delay the onset of thermal degradation of the plasticized polymer matrix. It was also pointed out, by WAXS and DSC analyses, that it exists a real competition between PEG 1000 and PLA for the intercalation into the interlayer spacing of the clay.</p>