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Steiner, E.
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article
Ring current and electron delocalisation in an all-metal cluster, Al42-
Abstract
<p>Localised-orbital analysis of the current density induced by a perpendicular magnetic field in square-planar A1<sub>4</sub><sup>2-</sup> demonstrates the intrinsic non-localisability of the σ electrons of this metallic cluster and confirms their dominant role in its diamagnetic ring current. Though delocalised, the π electrons do not give rise to a significant ring current.</p>