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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vilar, Vjp
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2022A Novel ceramic tubular membrane coated with a continuous graphene-TiO2 nanocomposite thin-film for CECs mitigationcitations
- 2022Tubular photobioreactors illuminated with LEDs to boost microalgal biomass productioncitations
- 2019Intensifying heterogeneous TiO2 photocatalysis for bromate reduction using the NETmix photoreactorcitations
- 2019Removal of bromate from drinking water using a heterogeneous photocatalytic mili-reactor: impact of the reactor material and water matrixcitations
- 2016Design of a fixed-bed ion-exchange process for the treatment of rinse waters generated in the galvanization process using Laminaria hyperborea as natural cation exchangercitations
- 2016Tertiary treatment of a municipal wastewater toward pharmaceuticals removal by chemical and electrochemical advanced oxidation processescitations
- 2015Incorporation of electrochemical advanced oxidation processes in a multistage treatment system for sanitary landfill leachatecitations
- 2015Degradation of trimethoprim antibiotic by UVA photoelectro-Fenton process mediated by Fe(III)-carboxylate complexescitations
- 2015Enhancement of a solar photo-Fenton reaction by using ferrioxalate complexes for the treatment of a synthetic cotton-textile dyeing wastewatercitations
- 2014Pore structure, interface properties and photocatalytic efficiency of hydration/dehydration derived TiO2/CNT compositescitations
- 2014Degradation of the antibiotic trimethoprim by electrochemical advanced oxidation processes using a carbon-PTFE air-diffusion cathode and a boron-doped diamond or platinum anodecitations
- 2012Insights into UV-TiO2 photocatalytic degradation of PCE for air decontamination systemscitations
- 2012Optimization of nickel biosorption by chemically modified brown macroalgae (Pelvetia canaliculata)citations
- 2012Adding value to marine macro-algae Laminaria digitata through its use in the separation and recovery of trivalent chromium ions from aqueous solutioncitations
- 2010Application of the Nernst-Planck approach to lead ion exchange in Ca-loaded Pelvetia canaliculatacitations
- 2007Modeling equilibrium and kinetics of metal uptake by algal biomass in continuous stirred and packed bed adsorberscitations
- 2007Methylene blue adsorption by algal biomass based materials: Biosorbents characterization and process behaviourcitations
Places of action
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article
Design of a fixed-bed ion-exchange process for the treatment of rinse waters generated in the galvanization process using Laminaria hyperborea as natural cation exchanger
Abstract
In this study, the removal of zinc from galvanization wastewaters was performed in a fixed bed column packed with brown macro-algae Laminaria hyperborea, acting as a natural cation exchanger (resin). The rinse wastewater presents a zinc concentration between 9 and 22 mg/L, a high concentration of light metals (mainly Na and Ca), a high conductivity (0.5-1.5 mS/cm) and a low organic content (DOC = 7 -15 mg C/L). The zinc speciation diagram showed that approximately 80% of zinc is in the form of Zn2+ and congruent to 20% as ZnSO4, considering the effluent matrix. From all operational conditions tested for zinc uptake (17 < bed height <27 cm, 4.5 < flow rate < 18.2 BV/h, 0.8 < particle equivalent diameter < 2.0 mm), the highest useful capacity (7.1 mg Zn/g algae) was obtained for D/dp = 31, LID = 11, 9.1 BV/h, tau = 6.4 min, corresponding to a service capacity of 124 BV (endpoint of 2 mg Zn/L). Elution was faster and near to 100% effective using 10 BV of HCl (1 M, 3.0%, 363 g HCl/L of resin), for flow rates higher than 4.5 BV/h. Calcium chloride solution (0.1 M) was selected as the best regenerant, allowing the reuse of the natural resin for more than 3 saturation/elution/regeneration cycles. The best operation conditions were scaled-up and tested in a pre-pilot plant. The scale-up design of the cation exchange process was proposed for the treatment of 2.4 m(3)/day of galvanization wastewater, resulting in an estimated reactants cost of 2.44 (sic)/m(3).