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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Batuk, Maria
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2023Impact of anionic ordering on the iron site distribution and valence states in oxyfluoride Sr2FeO3+xF1–x (x = 0.08, 0.2) with a layered perovskite networkcitations
- 2022The crystal and defect structures of polar KBiNb 2 O 7
- 2022The crystal and defect structures of polar KBiNb2O7
- 2022Topotactic redox cycling in SrFeO 2.5+δ explored by 3D electron diffraction in different gas atmospherescitations
- 2021Determination of Spinel Content in Cycled Li1.2Ni0.13Mn0.54Co0.13O2 Using Three-Dimensional Electron Diffraction and Precession Electron Diffractioncitations
- 2021Photoresistive gas sensor based on nanocrystalline ZnO sensitized with colloidal perovskite CsPbBr₃ nanocrystalscitations
- 2020Insight into the Mechanisms of High Activity and Stability of Iridium Supported on Antimony-Doped Tin Oxide Aerogel for Anodes of Proton Exchange Membrane Water Electrolyzerscitations
- 2020Magnetic ordering in the layered Cr(II) oxide arsenides Sr₂CrO₂Cr₂As₂ and Ba₂CrO₂Cr₂As₂citations
- 2018MnFe0.5Ru0.5O3: An Above-Room-Temperature Antiferromagnetic Semiconductorcitations
- 2017Grain-boundary engineering for aging and slow-crack-growth resistant zirconiacitations
- 2017Synthesis of MAX Phases in the Zr-Ti-Al-C Systemcitations
- 2016Effect of cation dopant radius on the hydrothermal stability of tetragonal zirconia: Grain boundary segregation and oxygen vacancy annihilationcitations
- 2016Strength, toughness and aging stability of highly-translucent Y-TZP ceramics for dental restorations
- 2015Effect of selenium content of CuInSex alloy nanopowder precursors on recrystallization of printed CuInSe2 absorber layers during selenization heat treatmentcitations
- 2015Effect of the burn-out step on the microstructure of the solution-processed Cu(In,Ga)Se-2 solar cellscitations
- 2015Process variability in Cu2ZnSnSe4 solar cell devices: Electrical and structural investigationscitations
- 2015Highly-translucent, strong and aging-resistant 3Y-TZP ceramics for dental restoration by grain boundary segregationcitations
- 2014Facile Synthesis of Ba1–xKxFe2As2 Superconductors via Hydride Routecitations
- 2014Mechanical synthesis of high purity Cu-In-Se alloy nanopowder as precursor for printed CISe thin film solar cellscitations
- 2014Microstructural analysis of 9.7% efficient Cu2ZnSnSe4 thin film solar cellscitations
- 2012Artificial construction of the layered Ruddlesden–Popper Manganite La2Sr2Mn3O10by reflection high energy electron diffraction monitored pulsed laser deposition
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article
Effect of selenium content of CuInSex alloy nanopowder precursors on recrystallization of printed CuInSe2 absorber layers during selenization heat treatment
Abstract
Polycrystalline CuInSe2 semiconductors are efficient light absorber materials for thin film solar cell technology, whereas printing is one of the promising low cost and non-vacuum approaches for the fabrication of thin film solar cells. The printed precursors are transformed into a dense polycrystalline CuInSe2 semiconductor film via thermal treatment in ambient selenium atmosphere (selenization). In this study, the effect of the selenium content in high purity mechanically synthesized CuInSex (x= 2, 1.5, 1 or 0.5) alloy precursors on the recrystallization of the CuInSe2 phase during the selenization process was investigated. The nanostructure and phase variation of CuInSex nanopowders were investigated by different characterization techniques. The recrystallization process of the 1-2 mu m thick CuInSex coatings into the CuInSe2 phase during selenization in selenium vapor was investigated via in-situ high temperature X-ray diffraction. The CuInSex precursors with lower selenium content showed a more pronounced phase conversion into CuInSe2 compared to the higher selenium content CuInSex precursors. Moreover, the CuInSex (x= 0.5 and 1) precursor resulted in a denser polycrystalline CuInSe2 semiconductor film with larger crystals. This could be attributed to a more intensive atomic interdiffusion within the CuInSex precursor system compared to a CuInSe2 phase precursor, and the formation of intermediate CuSe and CuSe2 fluxing phases during selenization. (C) 2014 Elsevier B.V. All rights reserved. ; This work is supported by the 'Strategic Initiative Materials' in Flanders (SIM) and the Institute for Innovation through Science and Technology in Flanders (IWT) under the Solution based Processing of Photovoltaic Modules (SoPPoM) program.