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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vantomme, Ghislaine
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Topics
Publications (9/9 displayed)
- 2023Photoswitchable Liquid-to-Solid Transition of Azobenzene-Decorated Polysiloxanescitations
- 2023Photoswitchable Liquid-to-Solid Transition of Azobenzene-Decorated Polysiloxanescitations
- 2021Photo-controlled alignment and helical organization in main-chain liquid crystalline alternating polymerscitations
- 2021Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Lightcitations
- 2021Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Lightcitations
- 2021Unraveling the Complexity of Supramolecular Copolymerization Dictated by Triazine-Benzene Interactionscitations
- 2017A rewritable, reprogrammable, dual light-responsive polymer actuatorcitations
- 2017Making waves in a photoactive polymer filmcitations
- 2017A four-blade light-driven plastic mill based on hydrazone liquid-crystal networkscitations
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article
A four-blade light-driven plastic mill based on hydrazone liquid-crystal networks
Abstract
The first light-driven plastic mill is developed, which converts the incoming light directly into a continuous rotation. This device is composed of four blades made of hydrazone-based liquid crystal polymer films able to bend under focused light irradiation and to create a force causing the rotation of the mill. The mechanism of motion originates from the fast photo-thermal isomerization around the C[dbnd]N bond of hydrazones. We show that by accelerating the rate of the thermal Z to E back-isomerization of hydrazones, macroscopic deformation with fast strain rate can be obtained. The rapid motion of the film is the key factor in obtaining the continuous rotatory motion of the mill. These results broaden the range of molecular switches available for macroscopic motion of light-driven organic devices and offer new insights for single-step energy conversion in soft robotics and automated systems.