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Caroli, Giuseppe
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article
Photochemical and thermal behavior of light-driven unidirectional molecular motor with long alkyl chains
Abstract
<p>In order to utilize molecular motors in a molecular device or smart materials, their dynamic behavior when other groups are introduced at key positions has to be examined. A C<sub>16</sub> hydrocarbon chain has been introduced at the stereogenic centers of the first generation light-driven molecular motor based on sterically overcrowded biphenanthrylidene. It was found that this derivatization does not affect the unidirectional rotary capability of the motor and does not cause a reduction of its speed, opening new possibility for future functionalizations and applications. © 2008 Elsevier Ltd. All rights reserved.</p>