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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tzounis, Lazaros
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024A hierarchically modified fibre-reinforced polymer composite laminate with graphene nanotube coatings operating as an efficient thermoelectric generatorcitations
- 2023Mineral-impregnated carbon-fiber based reinforcing grids as thermal energy harvesters: A proof-of-concept study towards multifunctional building materialscitations
- 2023Hierarchical CNT-coated basalt fiber yarns as smart and ultrasensitive reinforcements of cementitious matrices for crack detection and structural health monitoringcitations
- 2021An Approach toward the Realization of a Through-Thickness Glass Fiber/Epoxy Thermoelectric Generatorcitations
- 2021Role of sizing agent on the microstructure morphology and mechanical properties of mineral-impregnated carbon-fiber (MCF) reinforcement made with geopolymerscitations
- 2021Thermoelectric energy harvesting from single-walled carbon nanotube alkali-activated nanocomposites produced from industrial waste materialscitations
- 2020Electrical Joule heating of cementitious nanocomposites filled with multi-walled carbon nanotubescitations
- 2019Investigating the correlation between deactivation and the carbon deposited on the surface of Ni/Al2O3 and Ni/La2O3-Al2O3 catalysts during the biogas reforming reactioncitations
- 2019The relationship between reaction temperature and carbon deposition on nickel catalysts based on Al2O3, ZrO2 or SiO2 supports during the biogas dry reforming reactioncitations
- 2018All-aromatic SWCNT-Polyetherimide nanocomposites for thermal energy harvesting applicationscitations
- 2017Halloysite Nanotubes Noncovalently Functionalised with SDS Anionic Surfactant and PS-b-P4VP Block Copolymer for Their Effective Dispersion in Polystyrene as UV-Blocking Nanocomposite Filmscitations
- 2017Effect of MWCNTs and their modification on crystallization and thermal degradation of poly(butylene naphthalate)citations
- 2014Glass and Jute fibers modified with CNT-based functional coatings for high performance composites
- 2014β-nucleated propylene-ethylene random copolymer filled with multi-walled carbon nanotubes:Mechanical, thermal and rheological propertiescitations
- 2014β-nucleated propylene-ethylene random copolymer filled with multi-walled carbon nanotubescitations
Places of action
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article
Effect of MWCNTs and their modification on crystallization and thermal degradation of poly(butylene naphthalate)
Abstract
In the present work, poly(butylene naphthalate) (PBN) and its nanocomposites containing pristine multi - walled carbon nanotubes (MWCNTs), as well as functionalized MWCNTs with amino and carboxyl groups (MWCNTs-NH 2 and MWCNTs-COOH), were in situ prepared by applying the melt polycondensation method. From transmission electron microscopy (TEM) images, it was found that functionalized MWCNTs exhibited better dispersion into the polymer matrix compared to pristine MWCNTs. The nanocomposites showed faster crystallization rates compared to the neat material as proved by differential scanning calorimetry (DSC), due to the nucleating effect of the fillers. Finally, the presence of nanotubes and especially MWCNTs and MWCNTs-NH 2 favored formation of α-crystals while for both neat PBN and PBN/MWCNTs-COOH β-crystals were also formed. Thermal stability of the nanocomposites, studied by thermogravimetric analysis (TGA), was significantly increased due to the presence of MWCNTs, while a detailed study of the kinetics of the decomposition process was performed by pyrolysis-gas chromatography–mass spectroscopy (Py-GC/MS).