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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rudolf, Petra
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (62/62 displayed)
- 2024Understanding the Surface Chemistry of SnO 2 Nanoparticles for High Performance and Stable Organic Solar Cellscitations
- 2024Solvothermal Synthesis of Rare Earth Bisphthalocyaninescitations
- 2024Solvothermal Synthesis of Rare Earth Bisphthalocyaninescitations
- 2024Understanding the Surface Chemistry of SnO2 Nanoparticles for High Performance and Stable Organic Solar Cellscitations
- 2024Graphene growth from photo-polymerized bi-phenylthiol self-assembled monolayerscitations
- 2024Graphene growth from photo-polymerized bi-phenylthiol self-assembled monolayerscitations
- 2023Temperature-responsive and biocompatible nanocarriers based on clay nanotubes for controlled anti-cancer drug releasecitations
- 2023Temperature-responsive and biocompatible nanocarriers based on clay nanotubes for controlled anti-cancer drug releasecitations
- 2023Electrically Conductive and Highly Stretchable Piezoresistive Polymer Nanocomposites via Oxidative Chemical Vapor Depositioncitations
- 2023Electrically Conductive and Highly Stretchable Piezoresistive Polymer Nanocomposites via Oxidative Chemical Vapor Depositioncitations
- 2023Growth and Characterization of Carbon Nanofibers Grown on Vertically Aligned InAs Nanowires via Chemical Vapour Depositioncitations
- 2023Effect of intermolecular interactions on the glass transition temperature of chemically modified alternating polyketonescitations
- 2023Effect of intermolecular interactions on the glass transition temperature of chemically modified alternating polyketonescitations
- 2023Solvothermal synthesis of lanthanide-functionalized graphene oxide nanocompositescitations
- 2023Solvothermal synthesis of lanthanide-functionalized graphene oxide nanocompositescitations
- 2023Nickel Boride (Ni x B) Nanocrystals:From Solid-State Synthesis to Highly Colloidally Stable Inkscitations
- 2023Nickel Boride (NixB) Nanocrystalscitations
- 2022All-dry, one-step synthesis, doping and film formation of conductive polypyrrolecitations
- 2022All-dry, one-step synthesis, doping and film formation of conductive polypyrrolecitations
- 2022Comparative Study of Various Graphene Oxide Structures as Efficient Drug Release Systems for Ibuprofencitations
- 2021Boosting the Thermoelectric Properties of PEDOTcitations
- 2020New Porous Heterostructures Based on Organo-Modified Graphene Oxide for CO(2)Capturecitations
- 2020New Porous Heterostructures Based on Organo-Modified Graphene Oxide for CO(2)Capturecitations
- 2019Chemical Solution Deposition of Ordered 2D Arrays of Room-Temperature Ferrimagnetic Cobalt Ferrite Nanodotscitations
- 2018Electrically-Responsive Reversible Polyketone/MWCNT Network through Diels-Alder Chemistrycitations
- 2018Iron-substituted cubic silsesquioxane pillared clayscitations
- 2018Iron-substituted cubic silsesquioxane pillared clays:Synthesis, characterization and acid catalytic activitycitations
- 2018Magnetic functionality of thin film perovskite hybridscitations
- 2018Thermally induced chemical evolution in polyimide films investigated by X-ray photoelectron spectroscopycitations
- 2018Electrically-responsive reversible Polyketone/MWCNT network through Diels-Alder chemistrycitations
- 2016Band gap narrowing of Sns2 superstructures with improved hydrogen productioncitations
- 2016Band gap narrowing of SnS2 superstructures with improved hydrogen productioncitations
- 2016Mechanical, thermal and decomposition behavior of poly(epsilon-caprolactone) nanocomposites with clay-supported carbon nanotube hybridscitations
- 2015Comparing graphene growth on Cu(111) versus oxidized Cu(111)citations
- 2015Effect of surface reactions on steel, Al2O3 and Si3N4counterparts on their tribological performance with polytetrafluoroethylene filled compositescitations
- 2015Comparing Graphene Growth on Cu(111) versus Oxidized Cu(111)citations
- 2015Comparing Graphene Growth on Cu(111) versus Oxidized Cu(111)citations
- 2014Self-Assembly of Ferromagnetic Organic–Inorganic Perovskite-Like Filmscitations
- 2014Self-Assembly of Ferromagnetic Organic–Inorganic Perovskite-Like Filmscitations
- 2011Surface electronic and structural properties of nanostructured titanium oxide grown by pulsed laser depositioncitations
- 2011Spectroscopy and structural properties of amorphous and nanocrystalline silicon carbide thin filmscitations
- 2010A two-dimensional magnetic hybrid material based on intercalation of a cationic Prussian blue analog in montmorillonite nanoclaycitations
- 2010A Langmuir-Schaefer approach for the synthesis of highly ordered organoclay thin filmscitations
- 2009Effects of Acetate on Cation Exchange Capacity of a Zn-Containing Montmorillonitecitations
- 2009Key role of molecular kinetic energy in early stages of pentacene island growthcitations
- 2008Low band gap and ionic bonding with charge transfer, threshold in the polymeric lithium fulleride Li(4)C(60)citations
- 2008Cross-linking of multiwalled carbon nanotubes with polymeric aminescitations
- 2008Formation of carbon nanotubes on iron/cobalt oxides supported on zeolite-Ycitations
- 2008Photochromism and electrochemistry of a dithienylcyclopentene electroactive polymercitations
- 2008Photochromism and electrochemistry of a dithienylcyclopentene electroactive polymercitations
- 2007Characterization by X-ray photoemission spectroscopy of the open and closed forms of a dithienylethene switch in thin filmscitations
- 2006X-ray photoemission spectroscopy study on the effects of functionalization in fulleropyrrolidine and pyrrolidine derivativescitations
- 2006Clay-fulleropyrrolidine nanocompositescitations
- 2006Adsorption of fumaramide [2]rotaxane and its components on a solid substrate:A coverage-dependent studycitations
- 2006Adsorption of fumaramide [2]rotaxane and its components on a solid substratecitations
- 2005Nanostructured CNx (0 <x <0.2) films grown by supersonic cluster beam depositioncitations
- 2004Sealing of porous low-k dielectricscitations
- 2004Insulating surface layer on single crystal K3C60citations
- 2003Sealing of porous low-k dielectrics:an ellipsometric porosimetry study of UV-O3 oxidized SiOxCy filmscitations
- 2002Adsorption of a benzylic amide macrocycle on a solid substratecitations
- 2002Adsorption of a benzylic amide macrocycle on a solid substrate:XPS and HREELS characterization of thin films grown on Au(111)citations
- 2001A high resolution electron energy loss spectroscopy study of the adsorption of benzylic amide macrocycle on Au(111)citations
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article
Mechanical, thermal and decomposition behavior of poly(epsilon-caprolactone) nanocomposites with clay-supported carbon nanotube hybrids
Abstract
Poly(epsilon-caprolactone) (PCL) nanocomposites with hybrid clay-supported carbon nanotubes (Clay-CNT) in concentrations 0.5, 1.0 and 2.5 wt% were prepared by melt mixing. Mechanical, structural and thermal properties of the nanocomposites were studied. All nanocomposites exhibited similar stress-strain patterns to those of neat PCL but, with increasing nanofiller content yield point and Young's Modulus values increased, despite the absence of chemical interactions between PCL and Clay-CNT. It was also found that the crystallinity of the nanocomposites is the same as for neat PCL, but the nanofiller acts as nucleating agent which promotes the crystallization and also allows it to occur at higher temperatures. Thermal stability is instead negatively influenced by the nanofiller, since Clay-CNT catalyzes the decomposition of PCL at lower temperature. The monomer epsilon-caprolactone is the main decomposition product resulting from intramolecular esterification while cis-elimination at ester bonds (beta-hydrogen bond scission) is favored at higher temperatures. (C) 2016 Elsevier B.V. All rights reserved.