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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rodríguez, Rafael Lucena
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2022Mechanochemically designed bismuth-based halide perovskites for efficient photocatalytic oxidation of vanillyl alcoholcitations
- 2019Ultra-trace tellurium preconcentration and speciation analysis in environmental samples with a novel magnetic polymeric ionic liquid nanocomposite and magnetic dispersive micro-solid phase extraction with flow-injection hydride generation atomic fluorescence spectrometry detectioncitations
- 2018Efficient combined sorption/photobleaching of dyes promoted by cellulose/titania-based nanocomposite filmscitations
- 2017Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reactioncitations
- 2017Recycling polymer residues to synthesize magnetic nanocomposites for dispersive micro-solid phase extractioncitations
- 2016Selective extraction of Bactrocera oleae sexual pheromone from olive oil by dispersive magnetic microsolid phase extraction using a molecularly imprinted nanocomposite.citations
- 2015Polymer–nanoparticles composites in bioanalytical sample preparationcitations
- 2012Hybridization of commercial polymeric microparticles and magnetic nanoparticles for the dispersive micro-solid phase extraction of nitroaromatic hydrocarbons from water.citations
Places of action
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article
Recycling polymer residues to synthesize magnetic nanocomposites for dispersive micro-solid phase extraction
Abstract
he ubiquitous presence of plastics, an obvious consequence of their usefulness and low price, has turned them into a problem of environmental and safety concern. The new plastic economy, an initiative recently launched by the World Economic Forum and Ellen MacArthur Foundation, with analytical support from McKinsey & Company, promotes a change in the use of plastic worldwide around three main pillars: redesign, reusing and recycling. Recycled plastics, with the aim of extending their life spam, can be used to synthesize materials for analytical purposes. In this article polystyrene (PS) trays, previously used for food packaging, are proposed as polymeric source for the synthesis of magnetic nanocomposites. The synthesis plays with the solubility of PS in different solvents in such a way that PS is gelated in the presence of cobalt ferrite nanoparticles which are finally embedded in the polymeric network. The extraction capability of the magnetic PS nanocomposite was evaluated using the determination of four parabens (methylparaben, ethylparaben, propylparaben and butylparaben) in water using liquid chromatography-tandem mass spectrometry as model analytical problem. Under the optimum conditions, limits of detection and quantification were in the range of 0.05–0.15 and 0.15–0.5 ng/mL, respectively. The precisions, expressed as relative standard deviation (RSD), varied between 4.4% and 8.5% and the relative recoveries for analysis of the water samples were in the interval 81.2–104.5%.