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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mallet-Ladeira, Sonia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Synthesis, characterization, and inhibition effects of a novel eugenol derivative bearing pyrrole functionalities on the corrosion of mild steel in a HCl acid solutioncitations
- 2023Acetylacetonate Ruthenium Nitrosyls: A Gateway to Nitric Oxide Release in Water Under Near-Infrared Excitation by Two-Photon Absorptioncitations
- 2021Superconducting super-organized nanoparticles of the superconductor (BEDT-TTF)2Cu(NCS)2citations
- 2021Superconducting super-organized nanoparticles of the superconductor (BEDT-TTF)2Cu(NCS)2citations
- 2018Designed single-source precursors for iron germanide nanoparticles: colloidal synthesis and magnetic propertiescitations
- 2017Replacing two chlorido ligands by a bipyridine ligand in ruthenium nitrosyl complexes with NO-release capabilities: A comparative studycitations
- 2016Does the sign of the Cu–Gd magnetic interaction depend on the number of atoms in the bridge?citations
- 2015Iron Complexes with Stabilized Germylenes: Syntheses and Characterizationscitations
Places of action
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article
Superconducting super-organized nanoparticles of the superconductor (BEDT-TTF)2Cu(NCS)2
Abstract
The synthesis of (BEDT-TTF)2Cu(NCS)2 in the presence of poly(ethylene glycol) leads to super-organized nanoparticles of 2–8 nm size. Samples contain crystalline nanoparticles of the κ-(BEDT-TTF)2Cu(NCS)2 phase. The electrical conductivity at room temperature is about 0.08 S · cm–1, a typical value for nanopowders of tetrathiafulvalene-based conducting compounds. The current-voltage characteristic for an individual nanoparticle aggregate is fitted with a Shockley diode model. A saturation current of 4.1 pA and a threshold voltage of 0.45 V are extracted. N1s and S2p lines in X-ray photoelectron spectroscopy evidence a charge transfer, characteristic for tetrathiafulvalene-based conducting salts. Magnetic susceptibility studies show a superconducting transition at 9.1 K, a characteristic value for the κ-(BEDT-TTF)2Cu(NCS)2 phase. The thermoelectric power of the nanopowder is represented by the average //c and //b values for the single-crystal. Finally, resistivity for the nanopowder is nearly flat in the metallic region.