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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Asadi, Kamal
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2023Solution-processed multiferroic thin-films with large magnetoelectric coupling at room-temperaturecitations
- 2021Beyond 17% stable perovskite solar module via polaron arrangement of tuned polymeric hole transport layercitations
- 2021Mechanically stable solution-processed transparent conductive electrodes for optoelectronic applicationscitations
- 2021Mechanically stable solution-processed transparent conductive electrodes for optoelectronic applicationscitations
- 2020Synthesis and Solution Processing of Nylon-5 Ferroelectric Thin Filmscitations
- 2020Synthesis and solution processing of nylon-5 ferroelectric thin films : the renaissance of odd-nylons?
- 2019Thermodynamic approach to tailor porosity in piezoelectric polymer fibers for application in nanogeneratorscitations
- 2019Solution-processed transparent ferroelectric nylon thin filmscitations
- 2019Elastic wave propagation in smooth and wrinkled stratified polymer filmscitations
- 2016The negative piezoelectric effect of the ferroelectric polymer poly(vinylidene fluoride)citations
- 2016The negative piezoelectric effect of the ferroelectric polymer poly(vinylidene fluoride)citations
- 2016The negative piezoelectric effect of the ferroelectric polymer poly(vinylidene fluoride)citations
- 2016Retention of intermediate polarization states in ferroelectric materials enabling memories for multi-bit data storagecitations
- 2015Microstructured organic ferroelectric thin film capacitors by solution micromoldingcitations
- 2012Processing and Low Voltage Switching of Organic Ferroelectric Phase-Separated Bistable Diodescitations
- 2012Ferroelectric Phase Diagram of PVDF:PMMAcitations
- 2011Spinodal Decomposition of Blends of Semiconducting and Ferroelectric Polymerscitations
- 2010Retention Time and Depolarization in Organic Nonvolatile Memories Based on Ferroelectric Semiconductor Phase-Separated Blendscitations
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article
Mechanically stable solution-processed transparent conductive electrodes for optoelectronic applications
Abstract
<p>The bilayer structure of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) coating on silver nanowires (AgNWs) film is a promising structure for replacing indium tin oxide (ITO) as a flexible transparent conductive electrode. Pristine PEDOT:PSS film due to its hydrophilicity and high permeability cannot fully protect AgNWs from mechanical stress and oxidation. Here, we present a composite approach that improves mechanical properties and lifespan of the AgNWs/PEDOT:PSS electrode by adding polyvinyl alcohol (PVA) as a polymer-surfactant. It is shown that addition of PVA improves the conductivity as well as the stability of hybrid electrode under demanding mechanical stress conditions. The drop in conductivity of the hybrid electrode is only 17% after 2000 repeated bending cycles whereas the reference electrode has shown a dramatic drop of 180% in the conductivity. We speculate that generation of hydrogen bonds between PEDOT:PSS and PVA increases adhesivity and cohesivity of the conductive polymer film to the sublayer. So PEDOT:PSS-PVA film not only fixes the arrangement of AgNWs but also improves the welding on cross junction points. By addition of PVA, optoelectronic performance (Figure-of-merit (Φ<sub>TC</sub>)) of the electrode is improved from Φ<sub>TC</sub> = 2.646 × 10<sup>-3</sup> Ω<sup>-1</sup> for AgNWs/PEDOT:PSS to Φ<sub>TC</sub> = 3.819 × 10<sup>-3</sup> Ω<sup>-1</sup> for AgNWs/PEDOT:PSS-PVA electrode and power conversion efficiency (PCE) of the polymer solar cell (PSC) is increased by over 17%.</p>