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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Han, Li
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2020Interface fracture energy of contact layers in a solid oxide cell stackcitations
- 2018High-temperature thermoelectric properties of Na- and W-Doped Ca3Co4O9 system citations
- 2017Mid-IR optical properties of silicon doped InPcitations
- 2017Thermal operating window for PEDOT:PSS films and its related thermoelectric propertiescitations
- 2017Thermal operating window for PEDOT:PSS films and its related thermoelectric propertiescitations
- 2016On the Challenges of Reducing Contact Resistances in Thermoelectric Generators Based on Half-Heusler Alloyscitations
- 2016On the Challenges of Reducing Contact Resistances in Thermoelectric Generators Based on Half-Heusler Alloyscitations
- 2016On the Challenges of Reducing Contact Resistances in Thermoelectric Generators Based on Half-Heusler Alloyscitations
- 2016Effects of spark plasma sintering conditions on the anisotropic thermoelectric properties of bismuth antimony telluridecitations
- 2016Scandium-doped zinc cadmium oxide as a new stable n-type oxide thermoelectric materialcitations
- 2016Promising bulk nanostructured Cu2Se thermoelectrics via high throughput and rapid chemical synthesiscitations
- 2014Characterization of the interface between an Fe–Cr alloy and the p-type thermoelectric oxide Ca3Co4O9citations
- 2014The effect of setting velocity on the static and fatigue strengths of self-piercing riveted joints for automotive applications
- 2014Fabrication, spark plasma consolidation, and thermoelectric evaluation of nanostructured CoSb3citations
- 2014Characterization of the interface between an Fe–Cr alloy and the p -type thermoelectric oxide Ca 3 Co 4 O 9citations
- 2014Fabrication, spark plasma consolidation, and thermoelectric evaluation of nanostructured CoSb 3citations
- 2013The Influence of α- and γ-Al 2 O 3 Phases on the Thermoelectric Properties of Al-doped ZnOcitations
- 2013The Influence of α- and γ-Al2O3 Phases on the Thermoelectric Properties of Al-doped ZnOcitations
- 2008Formation and microstructure of (Ti, V)C-reinforeed iron-matrix composites using self-propagating high-temperature synthesis
- 2006Fretting behaviour of self-piercing riveted aluminium alloy joints under different interfacial conditions
Places of action
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article
Thermal operating window for PEDOT:PSS films and its related thermoelectric properties
Abstract
The intrinsically conducting polymer PEDOT:PSS is widely used and hasfound high recognition due to its excellent electrical conductivity. Itspotential applications cover many fields, e.g. thermoelectric energyconversion. Therefore we compared the thermoelectric propertiesofpristine and DMSO treated PEDOT:PSS films at potential operatingtemperatures. Here we observed the electrical degradation of the film upto complete failure. Further, the thermal aging of PEDOT:PSS stilllacks of understanding. It is pointed out that PEDOT:PSS films show acomplex degradation mechanism which includes a morphological and achemical part. In the range of room temperature and ∼160 °C PEDOT:PSSfilms follow the known exponential degradation which imposesmorphological degradation, while at higher temperatures this law is notsuitable to match the experimental data. Thus we extended the knownexponential equation by an additional exponential degradation term whichshows good agreement with the experimental data. The optical absorptionspectrum indicates a loss in bipolaron and polaron charge carriers,which reflects the degradation behavior. It can be seen that changes inthe optical absorption spectrum after isothermal annealing for more than50 h occur at temperatures around 120 °C, which marks the transitionfrom morphological to chemical degradation.