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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Day, P.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2016Phase boundary in the dimensionality of angle-dependent magnetoresistance oscillations in the charge-transfer salt α-(BEDT-TTF)2KHg(SCN)4citations
- 2007Molecular metals and superconductors: Crystal structures and physical properties of bis(ethylenedithio)-tetrathiafulvalene charge-transfer salts with FeX<inf>4</inf><sup>-</sup> (X = Cl or Br) anions
- 2007Molecular metals and superconductors: Structure and properties of tris[bis(ethylenedithio)tetrathiafulvalenium ]tetrachlorocopper(II) hydrate, (BEDT-TTF) <inf>3</inf>CuCl<inf>4</inf>·H<inf>2</inf>O: First evidence for coexistence of localized and conduction electrons in a metallic charge-transfer salt
- 2007Molecular metals and superconductors: Crystal structure and magnetism of (BEDT-TTF) <inf>2</inf>MCl<inf>4</inf>, (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene; M = Ga, Fe)
- 2007Molecular metals and superconductors: Crystal and electronic structures and electrical, magnetic, and optical properties of two copper tetrahalide salts of bis(ethylenedithio)-tetrathiafulvalene
- 2005Structures and physical properties of new ??-BEDT-TTF tris-oxalatometallate (III) salts containing chlorobenzene and halomethane guest moleculescitations
- 2005Structures and physical properties of new β′-BEDT-TTF tris-oxalatometallate (III) salts containing chlorobenzene and halomethane guest moleculescitations
- 2003New molecular charge-transfer salts of TM-TTF and BMDT-TTF with thiocyanate and selenocyanate complex anions [TMTTF = tetramethyltetrathiafulvalene; BMDT-TTF = bis(methylenedithio)tetrathiafulvalene]
- 2002Preparation, X-ray crystal structures and properties of α-(BEDT-TTF)[Fe(phen)(NCS)[· 2CHCl and (BEDT-TTF)]Cr(isoq) (NCS)[ (phen = 1,10-phenanthroline; Isoq = isoquinoline)citations
- 2002Synthesis, crystal structures and physical properties of TTF-based conducting charge transfer salts with anions containing selenocyanate ligandscitations
- 2001New molecular charge transfer salts of BEDT-TTF, Bis(ethylenedithio) tetrathiafulvalene, with thiocyanato-complex anions: (BEDT-TTF)[Fe(NCS)]·CHCl and (BEDT-TTF)[Cr(NCS)(bipym)]·0.15HOcitations
- 2001An unusual phase transition in the crystal structure and physical properties of (TTF)[MO(CN)]·4HO, where TTF = tetrathiafulvalene
Places of action
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article
Structures and physical properties of new ??-BEDT-TTF tris-oxalatometallate (III) salts containing chlorobenzene and halomethane guest molecules
Abstract
We report the structures and physical properties of new ??-(BEDT-TTF)4[Fe(oxalate)3]·G salts where A = H3O+, G = PhCl; A = Rb+ G = Pyridine. The structure of the PhCl salt is isomorphous with ??-(BEDT-TTF)4[(H3O)M(oxalate)3] with other guest molecules. PhCl is ordered in die hexagonal pockets formed by the [(H3O)Fe(oxalate)3] layer. The electrical conductivity is metallic down to 100 K, below which the resistivity increases with decreasing temperature. The specific conductivity at room temperature is about 10 S/cm. We also report the salt ??-(BEDT-TTF)4[RbFe(oxalate)3]·Pyridine where Rb+ replaces H3O. The electrical resistivity shows metallic behavior down to 100 K. and turns up gradually to a maximum at 65 K below which the system re-enters the metallic state down to liquid helium temperature. Neither salt shows superconductivity down to 2 K. In addition, other new ??-(BEDT-TTF)4[(H3O)M(oxalate)3]·salts with M = Cr, Ga, Fe; G = CH2Cl2, CH2ClBr, CH2Br2 are also reported.