| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Akutsu, H.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2021Asymmetric N-heteroacene tetracene analogues as potential n-type semiconductorscitations
- 20192D molecular superconductor to insulator transition in the β"-(BEDT-TTF)2[(H2O)(NH4)2M(C2O4)3]·18-crown-6 Series (M = Rh, Cr, Ru, Ir)citations
- 2019Effects of electron correlations and chemical pressures on superconductivity of β''-type organic compoundscitations
- 2015Radical-cation salt with novel BEDT-TTF packing motif containing tris(oxalato)germanate(IV)citations
- 2005Structures and physical properties of new ??-BEDT-TTF tris-oxalatometallate (III) salts containing chlorobenzene and halomethane guest moleculescitations
- 2005Structures and physical properties of new β′-BEDT-TTF tris-oxalatometallate (III) salts containing chlorobenzene and halomethane guest moleculescitations
Places of action
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article
Structures and physical properties of new ??-BEDT-TTF tris-oxalatometallate (III) salts containing chlorobenzene and halomethane guest molecules
Abstract
We report the structures and physical properties of new ??-(BEDT-TTF)4[Fe(oxalate)3]·G salts where A = H3O+, G = PhCl; A = Rb+ G = Pyridine. The structure of the PhCl salt is isomorphous with ??-(BEDT-TTF)4[(H3O)M(oxalate)3] with other guest molecules. PhCl is ordered in die hexagonal pockets formed by the [(H3O)Fe(oxalate)3] layer. The electrical conductivity is metallic down to 100 K, below which the resistivity increases with decreasing temperature. The specific conductivity at room temperature is about 10 S/cm. We also report the salt ??-(BEDT-TTF)4[RbFe(oxalate)3]·Pyridine where Rb+ replaces H3O. The electrical resistivity shows metallic behavior down to 100 K. and turns up gradually to a maximum at 65 K below which the system re-enters the metallic state down to liquid helium temperature. Neither salt shows superconductivity down to 2 K. In addition, other new ??-(BEDT-TTF)4[(H3O)M(oxalate)3]·salts with M = Cr, Ga, Fe; G = CH2Cl2, CH2ClBr, CH2Br2 are also reported.