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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Österberg, Monika
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024Biodegradation of Lignocellulose-Polyester Composite Films in Freshwater and Seawater Conditionscitations
- 2024Adsorption of sulphonated lignin-carbohydrate complexes (LCCs) onto cellulose surfaces
- 2024Hydrophobized lignin nanoparticle-stabilized Pickering foams : building blocks for sustainable lightweight porous materialscitations
- 2023Characterization of cell-biomaterial adhesion forces that influence 3D cell culture
- 2022Durable Biopolymer Films From Lignin-Carbohydrate Complex Derived From a Pulp Mill Side Streamcitations
- 2022Hybrid films from cellulose nanomaterials—properties and defined optical patternscitations
- 2021Durable Biopolymer Films From Lignin-Carbohydrate Complex Derived From a Pulp Mill Side Streamcitations
- 2021Cellulose nanofibers/lignin particles/tragacanth gum nanocomposite hydrogels for biomedical applications
- 2021Colloidal Lignin Particles and Epoxies for Bio-Based, Durable, and Multiresistant Nanostructured Coatingscitations
- 2021Tuning the functional properties of lignocellulosic films by controlling the molecular and supramolecular structure of lignincitations
- 2021Toward waste valorization by converting bioethanol production residues into nanoparticles and nanocomposite filmscitations
- 2020Three-Dimensional Printed Cell Culture Model Based on Spherical Colloidal Lignin Particles and Cellulose Nanofibril-Alginate Hydrogelcitations
- 2020Three-Dimensional Printed Cell Culture Model Based on Spherical Colloidal Lignin Particles and Cellulose Nanofibril-Alginate Hydrogelcitations
- 2020Observing microfibril bundles in wood by small-angle neutron scattering
- 2020Bundling of cellulose microfibrils in native and polyethylene glycol-containing wood cell walls revealed by small-angle neutron scatteringcitations
- 2020Moisture-related changes in the nanostructure of woods studied with X-ray and neutron scatteringcitations
- 2019Understanding hemicellulose-cellulose interactions in cellulose nanofibril-based compositescitations
- 2019Small-angle scattering model for efficient characterization of wood nanostructure and moisture behaviourcitations
- 2019Strong, Ductile, and Waterproof Cellulose Nanofibril Composite Films with Colloidal Lignin Particlescitations
- 2017Layer-by-layer assembled hydrophobic coatings for cellulose nanofibril films and textiles, made of polylysine and natural wax particles
- 2017Adsorption of Proteins on Colloidal Lignin Particles for Advanced Biomaterialscitations
- 2016Electrochemical detection of hydrogen peroxide on platinum-containing tetrahedral amorphous carbon sensors and evaluation of their biofouling propertiescitations
- 2015Correlation between cellulose thin film supramolecular structures and interactions with watercitations
- 2015Electrochemical detection of hydrogen peroxide on platinum-containing tetrahedral amorphous carbon sensors and evaluation of their biofouling propertiescitations
- 2013Non-ionic assembly of nanofibrillated cellulose and polyethylene glycol grafted carboxymethyl cellulose and the effect of aqueous lubrication in nanocomposite formationcitations
- 2012Interactions between inorganic nanoparticles and cellulose nanofibrilscitations
Places of action
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article
Toward waste valorization by converting bioethanol production residues into nanoparticles and nanocomposite films
Abstract
<p>A “waste-valorization” approach was developed to transform recalcitrant hydrolysis lignin (HL) from second-generation bioethanol production into multifunctional bio-based products. The hydrolysis lignin (HL) was extracted with aqueous acetone, yielding two fractions enriched in lignin and cellulose, respectively. The soluble hydrolysis lignin (SHL) was converted into anionic and cationic colloidal lignin particles (CLPs and c-CLPs). The insoluble cellulose-rich fraction was transformed into lignocellulosic nanofibrils that were further combined with CLPs or c-CLPs to obtain nanocomposite films with tailored mechanical properties, oxygen permeability and antioxidant properties. To enable prospective applications of lignin in nanocomposite films and beyond, CLPs and c-CLPs were also produced from a soda lignin (SL) and the influence of the lignin type on the particle size and ecotoxicity was evaluated. Finally, the carbon footprint of the entire process from hydrolysis lignin to films was assessed and an integration to industrial scale was considered to reduce the energy consumption. While most previous work utilizes purified lignin and pristine and often purified cellulose fibers to produce nanomaterials, this work provides a proof of concept for utilizing the recalcitrant lignin-rich side stream of the bioethanol process as raw material for functional nanomaterials and renewable composites.</p>