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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schlögl, Sandra
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Cationic UV-curing of bio-based epoxidized castor oil vitrimers with electrically conductive propertiescitations
- 2024Dual-vat photopolymerization 3D printing of vitrimerscitations
- 2024Reprocessable carbon fiber vitrimer composites: Reclamation and reformatting of carbon fibers for second generation composite materials
- 2024Rapid tooling for rubber extrusion molding by digital light processing 3D printing with dual curable vitrimerscitations
- 2024MetamaterialFindercitations
- 2024Redox cationic frontal polymerization: a rapid curing approach for carbon fiber-reinforced composites with high fiber contentcitations
- 2024Vitrimer Transition Phenomena from the Perspective of Thermal Volume Expansion and Shape (In)stabilitycitations
- 2024Design of Reversible Adhesives by Using a Triple Function of Ionic Liquidscitations
- 2023Accelerated Thermo-Catalytic Degradation of Perfluoropolyether (PFPE) Lubricants for Space Applicationscitations
- 2023Ti$_{40}$Zr$_{10}$Cu$_{36}$Pd$_{14}$ bulk metallic glass as oral implant materialcitations
- 2023Thermally Latent Bases in Dynamic Covalent Polymer Networks and their Emerging Applicationscitations
- 2023On‐Demand Activation of Transesterification by Chemical Amplification in Dynamic Thiol‐Ene Photopolymerscitations
- 2023Sustainable Bio-Based UV-Cured Epoxy Vitrimer from Castor Oilcitations
- 2023Redox cationic frontal polymerizationcitations
- 2023Ti40Zr10Cu36Pd14 bulk metallic glass as oral implant materialcitations
- 2022Influence of morphology and chemical surface composition on electrical conductivity of SiC microspherescitations
- 2022Asymmetric chiral and antichiral mechanical metamaterials with tunable Poisson's ratiocitations
- 2021High resolution additive manufacturing with acrylate based vitrimers using organic phosphates as transesterification catalystcitations
- 2021Structural Model for the Estimation of the Equivalent Permittivity of Nanodielectrics Based on Polyethylene and Epoxy Resins
- 2021Introduction of Photolatent Bases for Locally Controlling Dynamic Exchange Reactions in Thermo-Activated Vitrimerscitations
- 2021Investigating the influence of surface hardness and energy on the perceived stickiness of polymer coatings.
- 2021Role of Organic Phosphates and Phosphonates in Catalyzing Dynamic Exchange Reactions in Thiol-Click Vitrimerscitations
- 2021Functional mechanical metamaterial with independently tunable stiffness in the three spatial directionscitations
- 2020Tailored Interfaces in Fiber-Reinforced Elastomerscitations
- 2020Epoxy-anhydride vitrimers from aminoglycidyl resins with high glass transition temperature and efficient stress relaxationcitations
- 2020Design and characterisation of vitrimer-like elastomeric composites from HXNBR rubbercitations
- 2020Exploiting the Carbon and Oxa Michael Addition Reaction for the Synthesis of Yne Monomerscitations
- 2020Tribological characteristics of medical gloves in contact with human skin and skin equivalentscitations
- 2019Bonded aerospace repairs under tensile loading: Wet chemical surface treatment and selected environmental conditionscitations
- 2018Tailoring the interfaces in glass fiber-reinforced photopolymer compositescitations
- 2017Synthesis and evaluation of new radical photoinitiators bearing trialkoxysilyl groups for surface immobilizationcitations
- 2016Thiol-Ene versus Binary Thiol–Acrylate Chemistrycitations
- 2016Flexible epoxy based composites with enhanced delamination resistance
Places of action
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article
Influence of morphology and chemical surface composition on electrical conductivity of SiC microspheres
Abstract
<p>The present work provides a comparative study on the electrical properties (i.e. current-voltage characteristics) of spherically shaped SiC micro-sized particles that have been prepared by a thermal sintering process. As a typical field grading material, SiC exhibits a non-linear current-voltage behavior, which is exploited to reduce electrical stresses within composite materials. This is of particular interest in high-voltage applications to avoid material breakdown and to enhance the electrical components’ lifetime. As the current-voltage characteristics are affected by transport mechanisms at the grain contact, the electrical performance can be controlled by changing the chemical surface composition and morphology of the SiC particles. Advancing from irregular SiC flakes, the current work focuses on the electrical properties of SiC microspheres that have been tailored by applying selected thermal annealing steps and by chemical surface functionalization with organosilanes. The chemical surface composition of the microspheres prior to and after the modification step was studied by XPS and EDX, whilst SEM was employed to visualize the morphology of the particles’ surface and cross-section. In addition, the current-voltage characteristics were determined as a function of the particles’ morphology and chemical surface composition. The results clearly show that sintering aids, annealing temperature, morphology of particles and surface modification strongly govern the non-linear current-voltage behavior of SiC microspheres.</p>