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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lakard, Boris
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2024Polyaniline-Based Flexible Sensor for pH Monitoring in Oxidizing Environmentscitations
- 2024Fluorinated Polyaniline-Based Sensors with Enhanced NH3 Sensitivitycitations
- 2024Influence of surfactant on conductivity, capacitance and doping of electrodeposited polyaniline filmscitations
- 2024Polyaniline-based flexible sensors for pH monitoring
- 2023A novel conductometric sensor for acetone detection prepared through electro-polymerization of pyrrole-tailed ionic liquid
- 2022Investigation of polycarbazoles thin films prepared by electrochemical oxidation of 3- and 9-substituted carbazolescitations
- 2022Electrodeposition and Characterization of Conducting Polymer Films Obtained from Carbazole and 2-(9H-carbazol-9-yl)acetic Acidcitations
- 2022Strengthening adhesion of polycarbazole films on ITO surface by covalent electrografting of monomercitations
- 2021Development of new sticky and conducting polymer surfaces for MEMS applicationscitations
- 2021Investigation of electrochemical oxidative coupling of 3 and 6 substituted carbazolescitations
- 2019Conductive multilayer film based on composite materials made of conjugated polyelectrolytes and inorganic particles
- 2013Development of amperometric biosensors based on nanostructured tyrosinase-conducting polymer composite electrodescitations
- 2012Novel in situ electrochemical deposition of platinum nanoparticles by sinusoïdal voltages on conducting polymer films.citations
- 2012Novel in situ electrochemical deposition of platinum nanoparticles by sinusoïdal voltages on conducting polymer films.
- 2012Electrosynthesis and characterization of polymer films on silicon substrates for applications in micromanipulation.citations
- 2012Ammonia gas sensors based on polypyrrole films: Influence of electrodeposition parameterscitations
- 2011Characterization of the surface properties of polypyrrole films: Influence of electrodeposition parameters
- 2010Morphological and adhesive properties of polypyrrole films synthesized by sonoelectrochemical technique.citations
- 2010Morphological and adhesive properties of polypyrrole films synthesized by sonoelectrochemical technique.citations
- 2010Effect of various parameters on the conductivity of free standing electrosynthesized polypyrrole films
- 2010Electrochemically deposited polyethyleneimine films and their characterizationcitations
- 2010Morphological and adhesive properties of polypyrrole films synthesized by sonoelectrochemical techniquecitations
- 2008Effect of electrolyte solvent on the morphology of polypyrrole films. Application of the use of polypyrrole in pH sensorscitations
- 2007Potentiometric miniaturized pH sensors based on polypyrrole filmscitations
- 2007Development of miniaturized pH biosensors based on electrosynthesized polymer filmscitations
Places of action
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article
Strengthening adhesion of polycarbazole films on ITO surface by covalent electrografting of monomer
Abstract
Strong adhesion of a functional polymer coating to a solid support is a key requirement to achieve its robustness and high performance in different application areas. Herein, a novel carbazole derivative, 9-methyl-9H-carbazole-3,6-diamine (m-Cz-diamine), is synthesized and covalently grafted onto an ITO surface through the diazonium electroreduction method. The functionalization of the ITO surface is confirmed by XPS spectroscopy, water contact angle measurements and cyclic voltammetry analysis, revealing the covalent anchoring of an organic film (m-Cz-ITO). The functionalized ITO surface is then studied for oxidative electropolymerization of m-Cz-diamine and carbazole, showing clear advantages over a bare ITO substrate in terms of polymer film adhesion. The polymer films electrodeposited onto an electrografted ITO surface demonstrate very strong adhesion, as they do not delaminate, either by a scotch tape pulling, storing in air, or immersing under water for two months. On the other hand, the polymer films grown on a bare ITO substrate peel off easily in all the aforementioned stability tests. Therefore, electrografting an organic film onto the ITO surface clearly improves the adhesion of the polymer films on top of it. Moreover, it is interesting to note that the physicochemical properties of the polymer films deposited on the functionalized ITO substrate remain unchanged.