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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nabizadeh, Mohaddese
Vrije Universiteit Brussel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2023Operando odd random phase electrochemical impedance spectroscopy (ORP-EIS) for in-situ monitoring of the Zr-based conversion coating growth in the presence of (in)organic additivescitations
- 2023Investigation of hybrid Zr-aminosilane treatment formation on zinc substrate and comparison to advanced high strength stainless steelcitations
- 2022Unraveling the mechanism of the conversion treatment on Advanced High Strength Stainless Steels (AHSSS)citations
- 2022Unraveling the formation mechanism of hybrid Zr conversion coating on advanced high strength stainless steelscitations
- 2021The mechanism of thermal oxide film formation on low Cr martensitic stainless steel and its behavior in fluoride-based pickling solution in conversion treatmentcitations
Places of action
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article
Unraveling the formation mechanism of hybrid Zr conversion coating on advanced high strength stainless steels
Abstract
This research unravels the formation mechanism of a hybrid conversion treatment including the well-established Zr conversion coating with a silane-based organic additive and Cu-based inorganic additive. The deposition mechanism of this coating was investigated on the thermal oxide film of Advanced High Strength Stainless Steels (AHSSS). This coating has been characterized using advanced surface analytical techniques such as XPS, FEG-AES, GDOES, and ToF-SIMS. The results showed that the simultaneous presence of these two additives results in the formation of a donor-acceptor complex between amine groups and Cu ions. The final coating contains Cu oxide together with a Cu-aminosilane complex, Zr oxide deposited mainly around Cu oxide and the aminosilane layer on the outer surface.<br/>