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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Welter, E.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2021Half metallicity in Cr substituted Fe 2 TiSncitations
- 2019Atomic level structure of Ge-Sb-S glasses: Chemical short range order and long Sb-S bonds ; Struktura skel Ge-Sb-S na atomární úrovni: chemické uspořádání na krátkou vzdálenost a dlouhé vazby Sb-Scitations
- 2015Effect of Fe additive on the hydrogenation-dehydrogenation properties of 2LiH + MgB2/2LiBH4 + MgH2 systemcitations
- 2015Effect of Fe additive on the hydrogenation-dehydrogenation properties of $mathrm{2LiH + MgB_{2}/2LiBH_{4} + MgH_{2}}$ systemcitations
- 2011Characterization of Hydrogen Storage Materials and Systems with Photons and Neutronscitations
- 2011Investigation of metal distribution and carbide crystallite formation in metal-doped carbon films (a-C:Me, Me = Ti, V, Zr, W) with low metal contentcitations
- 2009On the chemical state and distribution of Zr- and V-based additives in reactive hydride compositescitations
- 2008Structural investigation of amorphous metal-doped carbon films
- 2007A versatile in situ spectroscopic cell fluorescence/transmission EXAFS and X-ray diffraction of heterogeneous catalysts in gas and liquid phasecitations
- 2003Evidence of icosahedral short-range order in Zr70Cu30 and Zr70Cu29Pd1 metallic glassescitations
- 2003Evidence of icosahedral short-range order in $mathrm{Zr_{70}Cu_{30}}$ and $mathrm{Zr_{70}Cu_{29}Pd_1}$ metallic glassescitations
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article
Investigation of metal distribution and carbide crystallite formation in metal-doped carbon films (a-C:Me, Me = Ti, V, Zr, W) with low metal content
Abstract
Metal-doped amorphous carbon films (a-C:Me) were deposited at room temperature by magnetron sputtering using a metal (Me = Ti, V, Zr, W) and a graphite target. The metal distribution and the temperature-induced carbide crystallite formation were analyzed by X-ray diffraction (XRD), electron microscopy (TEM, STEM) and X-ray absorption spectroscopy (EXAFS, XANES), focusing on low metal concentrations between 6.5 and 9.5%. In as-deposited samples, the metal atoms are atomically distributed in the carbon matrix without significant formation of carbide particles. With annealing to 900K the local atomic environment around the metal atoms becomes similar to the carbide. The carbide crystallites grow with annealing up to 1300K, their size is dependent on the metal type: V > Ti > Zr≈W. W2C and WC1-x crystallites were identified for W-doped films, whereas the monocarbides are formed for the other metals. It is demonstrated, that EXAFS and high resolution electron microscopy are required to get a correct picture of the structure of the analyzed a-C:W films. © 2011.