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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cordas, Cristina M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2021Bioelectricity generation using long-term operated biocathodecitations
- 2018Development of a ferrocenyl-based MIP in supercritical carbon dioxide: towards an electrochemical sensor for bisphenol Acitations
- 2018Imine ligands based on ferrocene: Synthesis, structural and Mössbauer characterization and evaluation as chromogenic and electrochemical sensors for Hg2+citations
- 2014Influence of respiratory substrate in carbon steel corrosion by a Sulphate Reducing Prokaryote model organismcitations
- 2011Bacterial diversity and influence of SRB presence on metal behaviour within the oil & gas industry
- 2004Overexpression and purification of Treponema pallidum rubredoxin; kinetic evidence for a superoxide-mediated electron transfer with the superoxide reductase neelaredoxincitations
- 2002EQCM study of polypyrrole modified electrodes doped with Keggin-type heteropolyanion for cation detectioncitations
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article
Development of a ferrocenyl-based MIP in supercritical carbon dioxide: towards an electrochemical sensor for bisphenol A
Abstract
<p>This work describes the development of a molecular imprinted polymer (MIP)-based disposable sensor for Bisphenol A (BPA). Ferrocenylmethyl methacrylate (FMMA) was co-polymerized with ethylene glycol dimethacrylate (EGDMA) for the first time using supercritical carbon dioxide (scCO<sub>2</sub>) as porogenic solvent. This polymer was developed with affinity for BPA by molecular imprinting technique and characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), average particle size diameter and particle size distribution. Binding performance was evaluated through affinity and selectivity tests in aqueous media. MIP performance as an electrochemical sensor was studied on commercial carbon screen-printed electrodes in the presence of BPA by differential pulse voltammetry. The results show the successful detection of the BPA characteristic irreversible oxidation peak, and the increase in the current intensity response with BPA concentration (4.7–8 nM), opening a route for the development of cost-effective disposable sensitive sensors for BPA using MIP.</p>