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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Madsen, Peter Jeppe
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Preparation of Block Copolymer-Stabilized Microspheres from Commercial Plastics and Their Use as Microplastic Proxies in Degradation Studiescitations
- 2023Enhancement of viscoelastic property of MABS processed by melt compounding and injection moldingcitations
- 2023Antimicrobial silicone skin adhesives facilitated by controlled octenidine release from glycerol compartmentscitations
- 2023Synthesis of poly(ethylene glycol)-co-poly(caprolactone) di- and triblock copolymers and effect of architecture, dispersity and end-functionalisation on their aqueous self-assemblycitations
- 2022One reaction to make highly stretchable or extremely soft silicone elastomers from easily available materialscitations
- 2021Toward a Design for Flowable and Extensible Ionomers: An Example of Diamine-Neutralized Entangled Poly(styrene-co-4-vinylbenzoic acid) Ionomer Meltscitations
- 2021Frequency dependent behavior of silicone slide-ring elastomers
- 2021Novel polyrotaxane cross-linkers as a versatile platform for slide-ring siliconecitations
- 2021Super-stretchable silicone elastomer applied in low voltage actuatorscitations
- 2020Linear Viscoelastic and Nonlinear Extensional Rheology of Diamine Neutralized Entangled Poly(styrene-co-4-vinylbenzoic acid) Ionomer Melts
- 2020Utilizing slide-ring cross-linkers in polysiloxane networks for softer dielectric elastomer actuatorscitations
- 2019Rheological and mechanical properties of polystyrene with hydrogen bonding
- 2019Incorporating polyrotaxane materials in dielectric elastomer actuators
- 2018Enhancing the electro-mechanical properties of polydimethylsiloxane elastomers through blending with poly(dimethylsiloxane-co-methylphenylsiloxane) copolymerscitations
- 2018Enhancing the electro-mechanical properties of polydimethylsiloxane elastomers through blending with poly(dimethylsiloxane-co-methylphenylsiloxane) copolymers Acknowledgments
- 2018Fabrication of microstructured binary polymer brush "corrals" with integral pH sensing for studies of proton transport in model membrane systemscitations
- 2008Supercritical fluids applied to the sol–gel process for preparation of AEROMOSILS/palladium particle nanocomposite catalystcitations
- 2008Facile Synthesis of Well-Defined Hydrophilic Methacrylic Macromonomers Using ATRP and Click Chemistrycitations
Places of action
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article
Supercritical fluids applied to the sol–gel process for preparation of AEROMOSILS/palladium particle nanocomposite catalyst
Abstract
A one-pot supercritical fluid (SCF) method was applied to prepare a series of silica aerogels. They were formed from alkoxysilanes by the sol–gel process directly in supercritical carbon dioxide. By this method no additional solvents are needed and the process of drying of wet gel afterwards is simplified. This method was modified by the addition of reactive polydimethylsiloxane (PDMS) chains, which yielded inorganically modified silicates, the so-called “ORMOSILS” or in our case “AEROMOSILS” when prepared in the form of aerogels. The investigation of the prepared materials by atomic force microscopy (AFM) showed that they consisted mainly of particles with a diameter of 50–100 nm. 2–3nm pores in these particles were indicated on the images. Further modification of the SCF method to yield AEROMOSILS with immobilized palladium particleswas successful. This material was tested as a catalyst both for batch and continuous supercritical hydrogenation of 2,5-dihydro-2,5-dimethoxy-furane.