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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Houben, Lothar
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024A Gd-doped ceria/TiOx nanocomposite as the active layer in a three terminal electrochemical resistivity switch.citations
- 2024W18O49 Nanowhiskers Decorating SiO2 Nanofibers: Lessons from In Situ SEM/TEM Growth to Large Scale Synthesis and Fundamental Structural Understandingcitations
- 2023W18O49 Nanowhiskers Decorating SiO2 Nanofiberscitations
- 2023Encapsulation of Uranium Oxide in Multiwall WS<sub>2</sub> Nanotubes
- 2022Polar Crystal Habit and 3D Electron Diffraction Reveal the Malaria Pigment Hemozoin as a Selective Mixture of Centrosymmetric and Chiral Stereoisomerscitations
- 2022Nanotubes from the Misfit Layered Compound (SmS)1.19TaS2citations
- 2022Nanotubes from the Misfit Layered Compound $(SmS)_{1.19}TaS_2$ : Atomic Structure, Charge Transfer, and Electrical Propertiescitations
- 2020Large lattice distortions and size-dependent bandgap modulation in epitaxial halide perovskite nanowirescitations
- 2020Large lattice distortions and size-dependent bandgap modulation in epitaxial halide perovskite nanowirescitations
- 2018Guided Growth of Horizontal ZnS Nanowires on Flat and Faceted Sapphire Surfacescitations
- 2018A Mechanistic Study of Phase Transformation in Perovskite Nanocrystals Driven by Ligand Passivationcitations
- 2016Tubular structures from the LnS–TaS₂ (Ln = La, Ce, Nd, Ho, Er) and LaSe–TaSe₂ misfit layered compoundscitations
- 2016From dilute isovalent substitution to alloying in CdSeTe nanoplateletscitations
- 2008Metadislocations in the orthorhombic structurally complex alloy Al13Co4citations
- 2006Atomic-resolution imaging of lattice imperfections in semiconductors by conjoined aberration-corrected HRTEM and exit-plane wavefunction retrievalcitations
- 2000Plasmaabscheidung von mikrokristallinem Silizium: Merkmale und Mikrostruktur und deren Deutung im Sinne von Wachstumsvorgängen
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article
A Gd-doped ceria/TiOx nanocomposite as the active layer in a three terminal electrochemical resistivity switch.
Abstract
<p>Coupling between an electrochemical reaction and a functional material property has been termed electro-chemo-X, or EC-X, where X can refer to mechanical, optical, magnetic or thermal properties. Recently, our group has demonstrated a two-terminal electro-chemo-mechanical (ECM) membrane actuator operating under ambient conditions and containing a Ce<sub>0.8</sub>Gd<sub>0.2</sub>O<sub>1.9</sub> solid electrolyte layer sandwiched between two Gd-doped ceria/TiO<sub>x</sub> nanocomposite thin films. Reducing one nanocomposite film while oxidizing the other was observed to produce reversible volume change thereby driving membrane actuator operation. Here, we use the same electrolyte and nanocomposite layer pair (the upper one as the ion reservoir and the lower, as the active layer) to further explore the EC-X effect. We demonstrate the suitability of the nanocomposite for a three-terminal, thin film-based resistivity switch. We find that application of ±6 V (<60 kV/cm) bias to the gate terminal for two hours under ambient conditions changes the nanocomposite conductivity in the channel between the source and drain by at least 40%. When the bias is negative, the active layer remains in a more highly conductive state for approximately twenty-four hours. Impedance spectroscopy and cyclic voltammetry reveal oxygen ion migration taking place between the active layer and the reservoir. X-ray photoelectron spectroscopy indicates that, in the absence of negative gate bias, thermal oxidation of Ce<sup>+3</sup> - > Ce<sup>+4</sup> is similarly effective in leading to increased nanocomposite conductivity, while reduction produces the opposite effect. With the expectation that the response time can be significantly shortened, the proposed resistivity switch may be suitable for future applications such as sensors, neuromorphic computing or spintronics.</p>