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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Talic, Belma
SINTEF
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Topics
Publications (16/16 displayed)
- 2022Fracture toughness of reactive bonded Co–Mn and Cu–Mn contact layers after long-term agingcitations
- 2022Protective Coatings for Ferritic Stainless Steel Interconnect Materials in High Temperature Solid Oxide Electrolyser Atmospherescitations
- 2021High toughness well conducting contact layers for solid oxide cell stacks by reactive oxidative bondingcitations
- 2020Comparison of MnCo2O4 coated Crofer 22 H, 441, 430 as interconnects for intermediate-temperature solid oxide fuel cell stackscitations
- 2020Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterizationcitations
- 2020Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterizationcitations
- 2020In-situ Fe-doped MnCo spinel coatings on Crofer 22 APU and AISI 441 interconnects: microstructural, electrical and oxidation properties
- 2020Comparison of MnCo 2 O 4 coated Crofer 22 H, 441, 430 as interconnects for intermediate-temperature solid oxide fuel cell stackscitations
- 2020Interface fracture energy of contact layers in a solid oxide cell stackcitations
- 2019Diffusion couple study of the interaction between Cr2O3 and MnCo2O4 doped with Fe and Cucitations
- 2019Diffusion couple study of the interaction between Cr 2 O 3 and MnCo 2 O 4 doped with Fe and Cucitations
- 2019Investigation of electrophoretic deposition as a method for coating complex shaped steel parts in solid oxide cell stackscitations
- 2018Thermal expansion and electrical conductivity of Fe and Cu doped MnCo2O4 spinelcitations
- 2018Thermal expansion and electrical conductivity of Fe and Cu doped MnCo 2 O 4 spinelcitations
- 2018Effect of pre-oxidation on the oxidation resistance of Crofer 22 APUcitations
- 2018Effect of pre-oxidation on the oxidation resistance of Crofer 22 APUcitations
Places of action
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article
Thermal expansion and electrical conductivity of Fe and Cu doped MnCo2O4 spinel
Abstract
Manganese cobalt spinel oxides are promising coating materials for corrosion protection of metallic interconnects in solid oxide fuel cell stacks. This work investigates how Fe and Cu doping affect the crystal structure, thermal expansion and electrical conductivity of the MnCo<sub>2−x</sub>M<sub>x</sub>O<sub>4</sub> (M = Cu, Fe; x = 0.1, 0.3, 0.5) spinel oxides. Single phase cubic spinels were successfully prepared by spray pyrolysis. The electrical conductivity between room temperature and 1000 °C increased with addition of Cu and decreased with addition of Fe. The thermal expansion coefficient (TEC) between 50 and 800 °C decreased from 14.4 to 11.0 × 10<sup>−6</sup> K<sup>−1</sup> going from MnCo<sub>2</sub>O<sub>4</sub> to MnCo<sub>1.5</sub>Fe<sub>0.5</sub>O<sub>4</sub>. The TEC of the Cu substituted materials did not follow any obvious trend with composition and was likely influenced by precipitation of CuO during heating. Based on their physical properties, the Fe doped materials are the most attractive for application as SOFC interconnect coatings.