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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nielsen, Jimmy
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2016Performance Factors and Sulfur Tolerance of Metal Supported Solid Oxide Fuel Cells with Nanostructured Ni:GDC Infiltrated Anodescitations
- 2015Performance Factors and Sulfur Tolerance of Metal Supported Solid Oxide Fuel Cells with Nanostructured Ni:GDC Infiltrated Anodescitations
- 2015Investigation of Novel Electrocatalysts for Metal Supported Solid Oxide Fuel Cells - Ru:GDCcitations
- 2014Impedance of SOFC electrodes: A review and a comprehensive case study on the impedance of LSM:YSZ cathodescitations
- 2013Infiltrated SrTiO3:FeCr‐based Anodes for Metal‐Supported SOFCcitations
- 2012Characterization of a well performing and durable Ni:CGO-infiltrated anode for metal-supported SOFC
- 2012Detailed impedance characterization of a well performing and durable Ni:CGO infiltrated cermet anode for metal-supported solid oxide fuel cellscitations
- 2012Infiltrated SrTiO3:FeCr-based anodes for metalsupported SOFC
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2012Break-down of Losses in High Performing Metal-Supported Solid Oxide Fuel Cells
- 2012Characterization of impregnated GDC nano structures and their functionality in LSM based cathodescitations
- 2011SOFC LSM:YSZ cathode degradation induced by moisture: An impedance spectroscopy studycitations
- 2011High performance metal-supported solid oxide fuel cells with Gd-doped ceria barrier layerscitations
- 2011Impedance of porous IT-SOFC LSCF:CGO composite cathodescitations
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article
Characterization of impregnated GDC nano structures and their functionality in LSM based cathodes
Abstract
Porous composite cathodes of LSM–YSZ (lanthanum strontium manganite and yttria stabilized zirconia) were impregnated with GDC (gadolinia doped ceria) nano particles. The impregnation process was varied using none or different surfactants (Triton X-45, Triton X-100, P123), and the quantity of impregnated GDC was varied via the precursor concentration and number of impregnation cycles. The obtained structures were characterized with Kr and N2 adsorption/desorption isotherms, mercury intrusion porosimetry, in-situ high temperature X-ray diffraction, scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). The performance of the impregnated LSM–YSZ cathode was correlated with the GDC load, and the density and connectivity of the GDC phase, whereas crystallite size and surface area appeared less significant. The impregnated GDC was indicated to be preferentially situated on the LSM phase and the LSM grain boundaries. The observations suggest that the improved performance associated with GDC nano particles is related to the particles placed near the TPB (triple phase boundary) zone. The GDC extends the TPB by creating an ionic conducting network on top of the LSM particles and on top of the insulating low conducting zirconates at the LSM–YSZ interface.