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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Thydén, Karl Tor Sune
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2018Deposition of highly oriented (K,Na)NbO3 films on flexible metal substratescitations
- 2016Effects of strong cathodic polarization of the Ni-YSZ interfacecitations
- 2016Comparison of ultramicrotomy and focused-ion-beam for the preparation of TEM and STEM cross section of organic solar cellscitations
- 2016Conductivity and structure of sub-micrometric SrTiO 3 -YSZ compositescitations
- 2016Conductivity and structure of sub-micrometric SrTiO3-YSZ compositescitations
- 2015Plasma properties during magnetron sputtering of lithium phosphorous oxynitride thin filmscitations
- 2015Fast mass interdiffusion in ceria/alumina compositecitations
- 2015Investigation of Novel Electrocatalysts for Metal Supported Solid Oxide Fuel Cells - Ru:GDCcitations
- 2014In situ surface reduction of a NiO-YSZ-alumina composite using scanning probe microscopycitations
- 2013Oxidation in ceria infiltrated metal supported SOFCs – A TEM investigationcitations
- 2013Oxidation in ceria infiltrated metal supported SOFCs – A TEM investigationcitations
- 2013Transmission Electron Microscopy Specimen Preparation Method for Multiphase Porous Functional Ceramicscitations
- 2013Transmission Electron Microscopy Specimen Preparation Method for Multiphase Porous Functional Ceramicscitations
- 2013Infiltrated SrTiO3:FeCr‐based Anodes for Metal‐Supported SOFCcitations
- 2013Infiltrated SrTiO 3 :FeCr‐based Anodes for Metal‐Supported SOFCcitations
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2012Characterization of impregnated GDC nano structures and their functionality in LSM based cathodescitations
- 2011Modifications of interface chemistry of LSM–YSZ composite by ceria nanoparticlescitations
- 2008Microstructural degradation of Ni-YSZ anodes for solid oxide fuel cells
- 2006Degradation of conductivity and microstructure under thermal and current load in Ni-YSZ cermets for SOFC anodescitations
Places of action
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article
Characterization of impregnated GDC nano structures and their functionality in LSM based cathodes
Abstract
Porous composite cathodes of LSM–YSZ (lanthanum strontium manganite and yttria stabilized zirconia) were impregnated with GDC (gadolinia doped ceria) nano particles. The impregnation process was varied using none or different surfactants (Triton X-45, Triton X-100, P123), and the quantity of impregnated GDC was varied via the precursor concentration and number of impregnation cycles. The obtained structures were characterized with Kr and N2 adsorption/desorption isotherms, mercury intrusion porosimetry, in-situ high temperature X-ray diffraction, scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). The performance of the impregnated LSM–YSZ cathode was correlated with the GDC load, and the density and connectivity of the GDC phase, whereas crystallite size and surface area appeared less significant. The impregnated GDC was indicated to be preferentially situated on the LSM phase and the LSM grain boundaries. The observations suggest that the improved performance associated with GDC nano particles is related to the particles placed near the TPB (triple phase boundary) zone. The GDC extends the TPB by creating an ionic conducting network on top of the LSM particles and on top of the insulating low conducting zirconates at the LSM–YSZ interface.