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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nowiński, Jan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2016Dependence of a glass transition temperature on a heating rate in DTA experiments for glasses containing transition metal oxidescitations
- 2016Nanocrystallisation in vanadate phosphate and lithium iron vanadate phosphate glassescitations
- 2015High electronic conductivity in nanostructured materials based on lithium-iron-vanadate-phosphate glassescitations
- 2013Isothermal nanocrystallization of vanadate-phosphate glassescitations
- 2013Novel vanadium-doped olivine-like nanomaterials with high electronic conductivitycitations
- 2011DSC and electrical conductivity studies on superionic all-glass phosphate-based composites
- 2011Electrical properties of the all-glass composite silver ion conductorscitations
- 2011Electrical properties and thermal stability of FePO4 glasses and nanomaterialscitations
- 2011Electrical properties vs. microstructure of nanocrystallized V2O5–P2O5 glasses — An extended temperature range studycitations
- 2011Electrical conductivity and phase transformations in the composite ionic conductors AgI : α-Al2O3 prepared via a high-pressure routecitations
- 2009Novel nanomaterials based on electronic and mixed conductive glassescitations
- 2009Correlation between electrical properties and microstructure of nanocrystallized V2O5–P2O5 glassescitations
- 2008Electrical properties and microstructure of glassy-crystalline Ag+-ion conducting composites synthesized by a high-pressure methodcitations
- 2007Nanocrystallization as a method of improvement of electrical properties and thermal stability of V2O5-rich glassescitations
- 2007Conductivity, thermal behavior and microstructure of new composites based on AgI–Ag2O–B2O3 glasses with Al2O3 matrixcitations
- 2006Conductivity and microstructure of silver borate glass/zirconia composites, prepared via a high pressure route
- 2006Effect of nanocrystallization on the electronic conductivity of vanadate-phosphate glassescitations
- 2006Crystallization processes in superionic AgI-Ag20-P205 ([Ag2O]/[P2O5] = 3) glasses
- 2004Enhancement of electrical conductivity in lithium vanadate glasses by nanocrystallizationcitations
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article
Electrical properties vs. microstructure of nanocrystallized V2O5–P2O5 glasses — An extended temperature range study
Abstract
An electronically conducting nanomaterial was synthesized by nanocrystallization of a 90V2O5·10P2O5 glass and its electrical properties were studied in an extended temperature range from − 170 to + 400 °C. The conductivity of the prepared nanomaterial reaches 2 ∙ 10− 1 S cm− 1 at 400 °C and 2 ∙ 10− 3 S cm− 1 at room temperature. It is higher than that of the original glass by a factor of 25 at room temperature and more than 100 below − 80 °C. A key role in the conductivity enhancement was ascribed to the material's microstructure, and in particular to the presence of the large number of small (ca. 20 nm) grains of crystalline V2O5. The observed conductivity dependencies are discussed in terms of the Mott's theory of the electronic hopping transport in disordered systems. Since V2O5 is known for its ability to intercalate lithium, the presented results might be helpful in the development of cathode materials for Li-ion batteries.