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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gierlotka, S.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2020High Pressure Quenched Glasses: unique structures and propertiescitations
- 2019Nanocrystalline NiAl intermetallic alloy with high hardness produced by mechanical alloying and hot-pressing consolidationcitations
- 2019NiAl-B composites with nanocrystalline intermetallic matrix produced by mechanical alloying and consolidationcitations
- 2011Electrical properties and thermal stability of FePO4 glasses and nanomaterialscitations
- 2011Electrical properties vs. microstructure of nanocrystallized V2O5–P2O5 glasses — An extended temperature range studycitations
- 2011Electrical conductivity and phase transformations in the composite ionic conductors AgI : α-Al2O3 prepared via a high-pressure routecitations
- 2009Correlation between electrical properties and microstructure of nanocrystallized V2O5–P2O5 glassescitations
- 2008Electrical properties and microstructure of glassy-crystalline Ag+-ion conducting composites synthesized by a high-pressure methodcitations
- 2007Conductivity, thermal behavior and microstructure of new composites based on AgI–Ag2O–B2O3 glasses with Al2O3 matrixcitations
- 2006Conductivity and microstructure of silver borate glass/zirconia composites, prepared via a high pressure route
- 2006SiC-Zn nanocomposites obtained using the high-pressure infiltration technique
- 2006TiC Nanocrystal Formation from Carburization of Laser-Grown Ti/O/C Nanopowders for Nanostructured Ceramicscitations
- 2005Elaboration of SiC, TiC and ZrC nanopowders by laser pyrolysis : from nanoparticles to ceramic nanomaterialscitations
- 2004Chapter 13. Microwave-Driven Hydrothermal Synthesis of Oxide Nanopowders for Applications in Optoelectronicscitations
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article
Electrical conductivity and phase transformations in the composite ionic conductors AgI : α-Al2O3 prepared via a high-pressure route
Abstract
Silver ion conducting composites of the general formula xAgI : (1 − x)α-Al2O3, where 0.2 ≤ x ≤ 0.8 (vol fraction) were prepared using a high-pressure synthesis route (T = 400 °C, p = 7.5 GPa). The microstructure of as-received rigid, non-brittle and dense samples was investigated by SEM. Other studies — DSC, XRD and impedance spectroscopy, were done as a function of temperature in the 20–200 °C temperature range. Close correlations were observed between the temperature dependences of the XRD patterns, the electrical conductivity and events seen on DSC traces. It was found out that the electrical conductivity at room temperature of all as-received composite materials was higher (by a factor between 7 and 100, depending on composition) than that measured after the heating–cooling cycle. This effect and other observed correlations were explained referring to the residual stress concept.