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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Garbarczyk, Jerzy
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2022Novel High-Pressure Nanocomposites for Cathode Materials in Sodium Batteriescitations
- 2021Towards Higher Electric Conductivity and Wider Phase Stability Range via Nanostructured Glass-Ceramics Processingcitations
- 2019Multifold pressure-induced increase of electric conductivity in LiFe<inf>0.75</inf>V<inf>0.10</inf>PO<inf>4</inf> glasscitations
- 2016Dependence of a glass transition temperature on a heating rate in DTA experiments for glasses containing transition metal oxidescitations
- 2016Synthesis of nanostructured Li3Me2(PO4)2F3 glass-ceramics (Me = V, Fe, Ti)citations
- 2016Nanocrystallisation in vanadate phosphate and lithium iron vanadate phosphate glassescitations
- 2015High electronic conductivity in nanostructured materials based on lithium-iron-vanadate-phosphate glassescitations
- 2013Isothermal nanocrystallization of vanadate-phosphate glassescitations
- 2013Novel vanadium-doped olivine-like nanomaterials with high electronic conductivitycitations
- 2011DSC and electrical conductivity studies on superionic all-glass phosphate-based composites
- 2011Electrical properties of the all-glass composite silver ion conductorscitations
- 2011Electrical properties and thermal stability of FePO4 glasses and nanomaterialscitations
- 2011Electrical properties vs. microstructure of nanocrystallized V2O5–P2O5 glasses — An extended temperature range studycitations
- 2011Electrical conductivity and phase transformations in the composite ionic conductors AgI : α-Al2O3 prepared via a high-pressure routecitations
- 2009Novel nanomaterials based on electronic and mixed conductive glassescitations
- 2009The thermal stability, local structure and electrical properties of lithium-iron phosphate glasses
- 2009Correlation between electrical properties and microstructure of nanocrystallized V2O5–P2O5 glassescitations
- 2008Electrical properties and microstructure of glassy-crystalline Ag+-ion conducting composites synthesized by a high-pressure methodcitations
- 2007Nanocrystallization as a method of improvement of electrical properties and thermal stability of V2O5-rich glassescitations
- 2007AgI-Ag2O-V2O5 glasses as ion-to-electron transducers for the construction of all-solid-state microelectrodescitations
- 2007Conductivity, thermal behavior and microstructure of new composites based on AgI–Ag2O–B2O3 glasses with Al2O3 matrixcitations
- 2006Conductivity and microstructure of silver borate glass/zirconia composites, prepared via a high pressure route
- 2006Effect of nanocrystallization on the electronic conductivity of vanadate-phosphate glassescitations
- 2006Crystallization processes in superionic AgI-Ag20-P205 ([Ag2O]/[P2O5] = 3) glasses
- 2006Ammonium- and nitrate-selective all-solid-state microelectrodes based on AgI-Ag2O-V2O5 glass transducer
- 2005A XANES study of the valence state of vanadium in lithium vanadate phosphate glassescitations
- 2004Enhancement of electrical conductivity in lithium vanadate glasses by nanocrystallizationcitations
- 2003Cyclic voltammetry and impedance spectroscopy studies of silver vanadate phosphate glassescitations
- 2001Ionic conductivity of glass-ceramic composites in the AgI-Ag<inf>2</inf>O-V<inf>2</inf>O<inf>5</inf> system
Places of action
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article
Electrical conductivity and phase transformations in the composite ionic conductors AgI : α-Al2O3 prepared via a high-pressure route
Abstract
Silver ion conducting composites of the general formula xAgI : (1 − x)α-Al2O3, where 0.2 ≤ x ≤ 0.8 (vol fraction) were prepared using a high-pressure synthesis route (T = 400 °C, p = 7.5 GPa). The microstructure of as-received rigid, non-brittle and dense samples was investigated by SEM. Other studies — DSC, XRD and impedance spectroscopy, were done as a function of temperature in the 20–200 °C temperature range. Close correlations were observed between the temperature dependences of the XRD patterns, the electrical conductivity and events seen on DSC traces. It was found out that the electrical conductivity at room temperature of all as-received composite materials was higher (by a factor between 7 and 100, depending on composition) than that measured after the heating–cooling cycle. This effect and other observed correlations were explained referring to the residual stress concept.