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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Palosz, B.
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Publications (7/7 displayed)
- 2011Electrical conductivity and phase transformations in the composite ionic conductors AgI : α-Al2O3 prepared via a high-pressure routecitations
- 2008Electrical properties and microstructure of glassy-crystalline Ag+-ion conducting composites synthesized by a high-pressure methodcitations
- 2007Conductivity, thermal behavior and microstructure of new composites based on AgI–Ag2O–B2O3 glasses with Al2O3 matrixcitations
- 2006Conductivity and microstructure of silver borate glass/zirconia composites, prepared via a high pressure route
- 2006SiC-Zn nanocomposites obtained using the high-pressure infiltration technique
- 2005Elaboration of SiC, TiC and ZrC nanopowders by laser pyrolysis : from nanoparticles to ceramic nanomaterialscitations
- 2004Chapter 13. Microwave-Driven Hydrothermal Synthesis of Oxide Nanopowders for Applications in Optoelectronicscitations
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article
Electrical properties and microstructure of glassy-crystalline Ag+-ion conducting composites synthesized by a high-pressure method
Abstract
Rigid, mechanically reinforced, composite Ag+-ion conductors based on xAgI·(100-x) (0.67Ag2O·0.33B2O3), 40 ≤ x ≤ 60, glasses and hard insulating powders of α-Al2O3 (2 µm) or ZrO2 (1 µm) were prepared by a high-pressure method. Microstructure of the composites, depended on the content of AgI in the glasses and the temperature of the high-pressure stage of the synthesis. In all cases, however, it consisted of the evenly distributed phases (conductive and insulating), which did not interpenetrate at a nanometer length scale. It was found that the high electrical conductivity of the composites, though somewhat lower than that of the glasses, generally followed the temperature- and composition dependencies of the latter. An important advantage of the composites over the corresponding glasses was their higher microhardness and non-brittleness, which, contrary to the glasses, enabled their post-synthesis machining, cutting or polishing.