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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Steil, Marlu César
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Topics
Publications (9/9 displayed)
- 2021Flash sintering of cationic conductive ceramics: A way to build multilayer systemscitations
- 2020Electrochemical Flash Sintering: A New Tool to Obtain All Solid-State Batteries in Few Secondscitations
- 2019Long-term stability of iron-doped calcium titanate CaTi0.9Fe0.1O3−δ oxygen transport membranes under non-reactive and reactive atmospherescitations
- 2018Oxygen pressure dependence of the ionic conductivity of iron-doped calcium titanatecitations
- 2016Preparation, characterization and sintering of yttrium-doped ThO2 for oxygen sensors applicationscitations
- 2015Flash sintering incubation in Al2O3/TZP compositescitations
- 2012Ionically conducting ceramics for soot oxidation. Mechanistic study with O-18(2) isotopic exchangecitations
- 2005Thermal stability and preparation of dense membrane ceramics of BIMEVOXcitations
- 2005Impedance study of the microstructure dependence of the electrical properties of BIMEVOXescitations
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article
Thermal stability and preparation of dense membrane ceramics of BIMEVOX
Abstract
The thermal stability and sintering conditions of a series of BIMEVOX compounds was studied. Extended annealing at temperature below the γ/γ′ phase transition, revealed the materials doped with a MeV cation are more stable than other BIMEVOXes. A modification of the BIMEVOX doped with a MeII metal was generally observed after annealing at 450 °C for several weeks. In contrast, no evolution was noticed for BISBVOX.15, BINBVOX.25, BITAVOX.20 compositions annealed for 10 weeks at 450 °C and 7 weeks at 500 °C. These latter compositions exhibit higher melting point and require sintering temperatures above 850 °C. Moreover, the increase in thermal expansion coefficient observed in these materials at the transition of phase is smaller (14 K− 1 to 14.5 K− 1) than for the other BIMEVOXes which makes them promising candidates as membrane for oxygen separators or catalytic dense membrane reactors.