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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Steil, Marlu César
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Topics
Publications (9/9 displayed)
- 2021Flash sintering of cationic conductive ceramics: A way to build multilayer systemscitations
- 2020Electrochemical Flash Sintering: A New Tool to Obtain All Solid-State Batteries in Few Secondscitations
- 2019Long-term stability of iron-doped calcium titanate CaTi0.9Fe0.1O3−δ oxygen transport membranes under non-reactive and reactive atmospherescitations
- 2018Oxygen pressure dependence of the ionic conductivity of iron-doped calcium titanatecitations
- 2016Preparation, characterization and sintering of yttrium-doped ThO2 for oxygen sensors applicationscitations
- 2015Flash sintering incubation in Al2O3/TZP compositescitations
- 2012Ionically conducting ceramics for soot oxidation. Mechanistic study with O-18(2) isotopic exchangecitations
- 2005Thermal stability and preparation of dense membrane ceramics of BIMEVOXcitations
- 2005Impedance study of the microstructure dependence of the electrical properties of BIMEVOXescitations
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article
Impedance study of the microstructure dependence of the electrical properties of BIMEVOXes
Abstract
Sintering conditions were determined for several BIMEVOX compounds. They are a function of the dopant and a careful investigation must be performed for each dopant. BIMEVOXes can be divided into two main groups: MEII doped BIMEVOXes such as Co, Cu, Ni, Zn and those doped with higher valence elements, MeV in particular such as Ta, Nb, Sn. The first group is characterised by low melting point and can be sintered at 750°C. In contrast, high melting point are observed for MeV doped compounds which must be sintered above 850°C. Relative density higher than 95% were obtained in all cases. Impedance spectroscopy revealed the electrical properties of a ceramic can be strongly dependant on its microstructure. Indeed, at low temperature, in the case of BICUVOX.10, lower conductivity was observed for sample with large grains.