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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fonseca, J.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2020Path Generation, Control, and Monitoringcitations
- 2019Graphene-poly(nickel complex) as novel electrochromic nanocomposite for the fabrication of a robust solid-state devicecitations
- 2019Printed Flexible mu-Thermoelectric Device Based on Hybrid Bi2Te3/PVA Compositescitations
- 2019Predicting the output dimensions, porosity and elastic modulus of additive manufactured biomaterial structures targeting orthopedic implantscitations
- 2017Graphene-poly(nickel complex) as novel electrochromic nanocomposite for the fabrication of a robust solid-state devicecitations
- 2016High-Performance Electrochromic Devices Based on Poly[Ni(salen)]-Type Polymer Filmscitations
- 2016New thermoresponsive eyedrop formulation containing ibuprofen loaded-nanostructured lipid carriers (NLC): Development, characterization and biocompatibility studies
- 2016New thermoresponsive eyedrop formulation containing ibuprofen loaded-nanostructured lipid carriers (NLC): Development, characterization and biocompatibility studies
- 2016New Thermoresponsive Eyedrop Formulation Containing Ibuprofen Loaded-Nanostructured Lipid Carriers (NLC): Development, Characterization and Biocompatibility Studiescitations
- 2011Modulating spectroelectrochemical properties of [Ni(salen)] polymeric films at molecular levelcitations
- 2010Solid-State Electrochromic Cells Based on [M(salen)]-Derived Electroactive Polymer Filmscitations
- 2010Insights into electronic and structural properties of novel Pd(II) salen-type complexescitations
- 2010Displacement estimation of a RC beam test based on TSS algorithm
- 2010Structural and electrochemical characterisation of [Pd(salen)]-type conducting polymer filmscitations
- 2008Electrocolorimetry of electrochromic materials on flexible ITO electrodescitations
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article
Electrocolorimetry of electrochromic materials on flexible ITO electrodes
Abstract
Electrochromic materials are characterized by their colour changes upon applied voltage. Colour can mean many things: a certain kind of light, its effect on the human eye, or the result of this effect in the mind of the viewer. Since the electrochromic materials are developed towards real life applications it is relevant to characterize them with the usual commercial colour standards. A colorimetric study of electrogenerated Prussian blue and electrogenerated polymers based on salen-type complexes of Cu(II), Ni(II) and Pd(H) deposited over transparent flexible electrodes of polyethylene terephthalate coated with indium tin oxide (PET/ITO electrodes) was carried out using the CIELAB coordinates. A cuvette with a designed adapter to allow potentiostatic control was placed on an integrating sphere installed in the sample compartment of a spectrophotometer to run the colorimetric measurements. The colour evolution in situ was measured through the transmittance of the films by potentiostatic control. Chronocoutometry/chronoabsorptometry was used to evaluate maximum coloration efficiencies for the coloration step: 184 (Pd), 161 (Cu) and 83 cm(2)/C (Ni) and for bleaching: 199 (Pd), 212 (Cu) and 173 cm(2)/C (Ni) of the Pd, Cu and Ni polymer films, respectively. The Prussian Blue/Prussian White states over the PET/ITO films were relatively reversible while the reversibility and stability of the polymers based on the metals salen-type complexes depends on the metal, Pd being the most stable.