| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Lee, Arie Van Der
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2022Synthesis and structural characterization of new ladder-like organostannoxanes derived from carboxylic acid derivatives: [C<sub>5</sub>H<sub>4</sub>N(<i>p</i>-CO<sub>2</sub>)]<sub>2</sub>[Bu<sub>2</sub>Sn]<sub>4</sub>(<i>μ</i> <sub> <i>3</i> </sub>-O)<sub>2</sub>(<i>μ</i> <sub> <i>2</i> </sub>-OH)<sub>2</sub>, [Ph<sub>2</sub>CHCO<sub>2</sub>]<sub>4</sub>[Bu<sub>2</sub>Sn]<sub>4</sub>(<i>μ</i> <sub> <i>3</i> </sub>-O)<sub>2</sub>, and [(<i>p</i>-NH<sub>2</sub>)-C<sub>6</sub>H<sub>4</sub>-CO<sub>2</sub>]<sub>2</sub>[Bu<sub>2</sub>Sn]<sub>4</sub>(<i>μ</i> <sub> <i>3</i> </sub>-O)<sub>2</sub>(<i>μ</i> <sub> <i>2</i> </sub>-OH)<sub>2</sub>citations
- 2022The Unexpected Helical Supramolecular Assembly of a Simple Achiral Acetamide Tecton Generates Selective Water Channelscitations
- 2019High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1citations
- 2012Relationship between wood elastic strain under bending and cellulose crystal straincitations
- 2003X-ray reflectometry characterization of SON 68 glass alteration films
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article
High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1
Abstract
A silicalite-1/bismuth composite was synthesized by insertion of liquid bismuth in the 5.5 Å diameter pores of the zeolite under high-pressure, high-temperature conditions. The insertion of bismuth stabilizes the structure with respect to pressure-induced amorphization. Transmission electron microscopy indicated the presence of chains of atoms, which correspond to the 5.5 Å diameter of the host silicalite-1 structure. Neutron powder diffraction also confirmed the insertion of Bi in the pores of silicalite-1. Density functional theory calculations indicate that the insertion of bismuth results in formation of chains with short and long Bi-Bi distances in the pores of the host silicalite-1 linked to the framework by van der Waal's interactions. The material is predicted to be a semiconductor with a band gap of 0.4 eV.