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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hansen, Thomas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Newly developed aerodynamic levitation device for neutron scattering experiments
- 2024Impact of Mn/Ni and Li/(Mn+Ni) ratios on phase equilibrium and electrochemical performance of the high voltage spinel LiNi0.5Mn1.5O4citations
- 2023Magnetic and structural properties of the iron silicide superconductor LaFeSiH
- 2022An Easy-to-Use Custom-Built Cell for Neutron Powder Diffraction Studies of Rechargeable Batteriescitations
- 2022An Easy‐to‐Use Custom‐Built Cell for Neutron Powder Diffraction Studies of Rechargeable Batteriescitations
- 2021Investigation into the magnetic properties of CoFeNiCryCux alloyscitations
- 2021Investigation into the magnetic properties of CoFeNiCryCux alloyscitations
- 2020High-pressure, high temperature synthesis of a mesoporous α-quartz/bismuth nanowire compositecitations
- 2020Structural Characteristics of Fresh, Thermally Aged, Poisoned and Regenerated Pt-Pd Catalysts Studied by Analytical Transmission Electron Microscopy
- 2019High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1citations
- 2017Absence of magnetic long range order in Y2CrSbO7: bond-disorder induced magnetic frustration in a ferromagnetic pyrochlorecitations
- 2015Expression, receptor binding, and biophysical characterization of guinea pig insulin desB30citations
- 2013Reduction of Sr2MnO4 investigated by high temperature in situ neutron powder diffraction under hydrogen flow.citations
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article
High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1
Abstract
A silicalite-1/bismuth composite was synthesized by insertion of liquid bismuth in the 5.5 Å diameter pores of the zeolite under high-pressure, high-temperature conditions. The insertion of bismuth stabilizes the structure with respect to pressure-induced amorphization. Transmission electron microscopy indicated the presence of chains of atoms, which correspond to the 5.5 Å diameter of the host silicalite-1 structure. Neutron powder diffraction also confirmed the insertion of Bi in the pores of silicalite-1. Density functional theory calculations indicate that the insertion of bismuth results in formation of chains with short and long Bi-Bi distances in the pores of the host silicalite-1 linked to the framework by van der Waal's interactions. The material is predicted to be a semiconductor with a band gap of 0.4 eV.